Fourier sine and cosine series

The Thomas–Fermi (TF) model, named after Llewellyn Thomas and Enrico Fermi, is a quantum mechanical theory for the electronic structure of many-body systems developed semiclassically shortly after the introduction of the Schrödinger equation. It stands separate from wave function theory as being formulated in terms of the electronic density alone and as such is viewed as a precursor to modern density functional theory. The TF model is correct only in the limit of an infinite nuclear charge. Using the approximation for realistic systems yields poor quantitative predictions, even failing to reproduce some general features of the density such as shell structure in atoms and Friedel oscillations in solids. It has, however, found modern applications in many fields through the ability to extract qualitative trends analytically and with the ease at which the model can be solved. The kinetic energy expression of Thomas–Fermi theory is also used as a component in more sophisticated density approximation to the kinetic energy within modern orbital-free density functional theory.

Working independently, Thomas and Fermi used this statistical model in 1927 to approximate the distribution of electrons in an atom. Although electrons are distributed nonuniformly in an atom, an approximation was made that the electrons are distributed uniformly in each small volume element ΔV (i.e. locally) but the electron density $n({\vec {r}})$ can still vary from one small volume element to the next.

Kinetic energy

For a small volume element ΔV, and for the atom in its ground state, we can fill out a spherical momentum space volume V_f  up to the Fermi momentum p_f , and thus,

$V_{f}={\frac {4}{3}}\pi p_{f}^{3}({\vec {r}}).$

where ${\vec {r}}$ is a point in ΔV.

The corresponding phase space volume is

$\Delta V_{ph}=V_{f}\ \Delta V={\frac {4}{3}}\pi p_{f}^{3}({\vec {r}})\ \Delta V.$

The electrons in ΔV_ph  are distributed uniformly with two electrons per h³ of this phase space volume, where h is Planck's constant. Then the number of electrons in ΔV_ph  is

$\Delta N_{ph}={\frac {2}{h^{3}}}\ \Delta V_{ph}={\frac {8\pi }{3h^{3}}}p_{f}^{3}({\vec {r}})\ \Delta V.$

The number of electrons in ΔV  is

$\Delta N=n({\vec {r}})\ \Delta V$

where $n({\vec {r}})$ is the electron density.

Equating the number of electrons in ΔV to that in ΔV_ph  gives,

$n({\vec {r}})={\frac {8\pi }{3h^{3}}}p_{f}^{3}({\vec {r}}).$

The fraction of electrons at ${\vec {r}}$ that have momentum between p and p+dp is,

${\begin{aligned}F_{\vec {r}}(p)dp&={\frac {4\pi p^{2}dp}{{\frac {4}{3}}\pi p_{f}^{3}({\vec {r}})}}\qquad \qquad p\leq p_{f}({\vec {r}})\\&=0\qquad \qquad \qquad \quad {\text{otherwise}}\\\end{aligned}}$

Using the classical expression for the kinetic energy of an electron with mass m_e, the kinetic energy per unit volume at ${\vec {r}}$ for the electrons of the atom is,

${\begin{aligned}t({\vec {r}})&=\int {\frac {p^{2}}{2m_{e}}}\ n({\vec {r}})\ F_{\vec {r}}(p)\ dp\\&=n({\vec {r}})\int _{0}^{p_{f}({\vec {r}})}{\frac {p^{2}}{2m_{e}}}\ \ {\frac {4\pi p^{2}}{{\frac {4}{3}}\pi p_{f}^{3}({\vec {r}})}}\ dp\\&=C_{F}\ [n({\vec {r}})]^{5/3}\end{aligned}}$

where a previous expression relating $n({\vec {r}})$ to $p_{f}({\vec {r}})$ has been used and,

$C_{F}={\frac {3h^{2}}{10m_{e}}}\left({\frac {3}{8\pi }}\right)^{\frac {2}{3}}.$

Integrating the kinetic energy per unit volume $t({\vec {r}})$ over all space, results in the total kinetic energy of the electrons,

$T=C_{F}\int [n({\vec {r}})]^{5/3}\ d^{3}r\ .$

This result shows that the total kinetic energy of the electrons can be expressed in terms of only the spatially varying electron density $n({\vec {r}}),$ according to the Thomas–Fermi model. As such, they were able to calculate the energy of an atom using this expression for the kinetic energy combined with the classical expressions for the nuclear-electron and electron-electron interactions (which can both also be represented in terms of the electron density).

Potential energies

The potential energy of an atom's electrons, due to the electric attraction of the positively charged nucleus is,

$U_{eN}=\int n({\vec {r}})\ V_{N}({\vec {r}})\ d^{3}r\,$

where $V_{N}({\vec {r}})\,$ is the potential energy of an electron at ${\vec {r}}\,$ that is due to the electric field of the nucleus. For the case of a nucleus centered at ${\vec {r}}=0$ with charge Ze, where Z is a positive integer and e is the elementary charge,

$V_{N}({\vec {r}})={\frac {-Ze^{2}}{r}}.$

The potential energy of the electrons due to their mutual electric repulsion is,

$U_{ee}={\frac {1}{2}}\ e^{2}\int {\frac {n({\vec {r}})\ n({\vec {r}}\,')}{\left\vert {\vec {r}}-{\vec {r}}\,'\right\vert }}\ d^{3}r\ d^{3}r'.$

Total energy

The total energy of the electrons is the sum of their kinetic and potential energies,

${\begin{aligned}E&=T\ +\ U_{eN}\ +\ U_{ee}\\&=C_{F}\int [n({\vec {r}})]^{5/3}\ d^{3}r\ +\int n({\vec {r}})\ V_{N}({\vec {r}})\ d^{3}r\ +\ {\frac {1}{2}}\ e^{2}\int {\frac {n({\vec {r}})\ n({\vec {r}}\,')}{\left\vert {\vec {r}}-{\vec {r}}\,'\right\vert }}\ d^{3}r\ d^{3}r'\\\end{aligned}}$

Inaccuracies and improvements

Although this was an important first step, the Thomas–Fermi equation's accuracy is limited because the resulting expression for the kinetic energy is only approximate, and because the method does not attempt to represent the exchange energy of an atom as a conclusion of the Pauli principle. A term for the exchange energy was added by Dirac in 1928.

However, the Thomas–Fermi–Dirac theory remained rather inaccurate for most applications. The largest source of error was in the representation of the kinetic energy, followed by the errors in the exchange energy, and due to the complete neglect of electron correlation.

In 1962, Edward Teller showed that Thomas–Fermi theory cannot describe molecular bonding – the energy of any molecule calculated with TF theory is higher than the sum of the energies of the constituent atoms. More generally, the total energy of a molecule decreases when the bond lengths are uniformly increased. This can be overcome by improving the expression for the kinetic energy.

The Thomas–Fermi kinetic energy can be improved by adding to it the Weizsäcker (1935) correction:, which can then make a much improved Thomas–Fermi–Dirac–Weizsaecher density functional theory (TFDW-DFT), which would be equivalent to the Hartree and then Hartree-Fock mean field theories which do not treat static electron correlation (treated by the CASSCF theory developed by Bjorn Roos' group in Lund, Sweden), and dynamic correlation (treated by both Moeller–Plesset perturbation theory to second order (MP2) or CASPT2, the extension of MP2 theory to systems not well treated by simple single reference/configuration methods like Hartree–Fock theory and Kohn–Sham DFT. Note that KS-DFT has also been extended to treat systems for which the ground electronic state is not well represented by either a single Slater determinant of Hartree–Fock or "Kohn–Sham" orbitals, the so-called CAS-DFT method, also being developed in the group of Bjorn Roos in Lund.

$T_{W}={\frac {1}{8}}{\frac {\hbar ^{2}}{m}}\int {\frac {|\nabla n({\vec {r}})|^{2}}{n({\vec {r}})}}dr.$

See also

• Thomas–Fermi approximation for the degeneracy of states

References

1. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
   
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2. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
   
   My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
3. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
   
   My blog: http://www.primaboinca.com/view_profile.php?userid=5889534

Footnotes

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