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{{About|high-pressure physics of minerals|physical attributes of minerals like [[Cleavage (crystal)|cleavage]] |Mineralogy#physical mineralogy}}
{{No footnotes|date=May 2011}}
'''Mineral physics''' is the science of materials that compose the interior of planets, particularly the Earth. It overlaps with [[petrophysics]], which focuses on whole-rock properties. It provides information that allows interpretation of surface measurements of [[seismic wave]]s, [[gravity anomalies]], [[geomagnetic field]]s and [[magnetotellurics|electromagnetic]] fields in terms of properties in the deep interior of the Earth. This information can be used to provide insights into [[plate tectonics]], [[mantle convection]], the [[geodynamo]] and related phenomena.


Laboratory work in mineral physics require high pressure measurements. The most common tool is a [[diamond anvil]] cell, which uses diamonds to put a small sample under pressure that can approach the conditions in the Earth's interior.
'''Time–frequency analysis for music signals''' is one of the applications of [[time–frequency analysis]]. Musical sound can be more complicated than human vocal sound, occupying a wider band of frequency. Music signals are time-varying signals; while the classic Fourier transform is not sufficient to analyze them, time–frequency analysis is an efficient tool for such use.  Time–frequency analysis is extended from the classic Fourier approach.  [[Short-time Fourier transform]] (STFT), [[Gabor transform]] (GT) and [[Wigner distribution function]] (WDF) are famous time–frequency methods, useful for analyzing music signals such as notes played on a piano, a flute or a guitar.


== Creating high pressures ==
==Knowledge about music signal==
The pace of progress in mineral physics has been determined, to a large extent, by the technology for reproducing the high pressures and temperatures in the Earth's interior. The most common tools for achieving this have been:


===Shock compression===
Music is a type of sound that has some stable frequencies in a time period. Music can be produced by several methods. For example, the sound of a piano is produced by striking [[Strings (music)|strings]], and the sound of a violin is produced by [[Bow (music)|bowing]]. All musical sounds have their [[fundamental frequency]] and overtones. Fundamental frequency is the lowest frequency in harmonic series. In a periodic signal, the fundamental frequency is the inverse of the period length. Overtones are integer multiples of the fundamental frequency.
Many of the pioneering studies in mineral physics involved explosions or projectiles that subjected a sample to a shock. For a brief time interval, the sample is under pressure as the shock wave passes through. Pressures as high as any in the Earth have been achieved by this method. However, the method has some disadvantages. The pressure is very non-uniform and is not [[adiabatic]], so the pressure wave heats the sample up in passing. The conditions of the experiment must be interpreted in terms of a set of pressure-density curves called the '''Hugoniot curves'''.<ref>{{cite journal
|last=Ahrens
|first=T. J.
|year=1980
|title=Dynamic compression of Earth materials
|journal=[[Science (journal)|Science]]
|volume=207
|pages=1035–1041
|bibcode = 1980Sci...207.1035A |doi = 10.1126/science.207.4435.1035
|issue=4435}}</ref>


===Multi-anvil press===
:{| class="wikitable" border="1"
Multi-anvil presses involve an arrangement of anvils to concentrate pressure from a press onto a sample. Typically the apparatus uses an arrangement eight cube-shaped [[tungsten carbide]] anvils to compress a ceramic octahedron containing the sample and a ceramic or Re metal furnace. The anvils are typically placed in a large hydraulic press. The method was developed by Kawai and Endo in Japan.<ref>{{cite journal|last=Kawai|first=Naoto|title=The generation of ultrahigh hydrostatic pressures by a split sphere apparatus|journal=Review of Scientific Instruments|year=1970|volume=41|issue=8|pages=1178&ndash;1181|doi=10.1063/1.1684753|bibcode = 1970RScI...41.1178K }}</ref> Unlike shock compression, the pressure exerted is steady, and the sample can be heated using a furnace. Pressures of about 28 GPa (equivalent to depths of 840&nbsp;km),<ref>{{cite journal|last=Kubo|first=Atsushi|author2=Akaogi, Masaki|title=Post-garnet transitions in the system Mg4Si4O12–Mg3Al2Si3O12 up to 28 GPa: phase relations of garnet, ilmenite and perovskite|journal=Physics of the Earth and Planetary Interiors|year=2000|volume=121|issue=1-2|pages=85–102|doi=10.1016/S0031-9201(00)00162-X|bibcode = 2000PEPI..121...85K }}</ref> and temperatures above 2300&nbsp;°C,<ref>{{cite journal|last=Zhang|first=Jianzhong|author2=Liebermann, Robert C. |author3=Gasparik, Tibor |author4=Herzberg, Claude T. |author5=Fei, Yingwei |title=Melting and subsolidus relations of silica at 9 to 14 GPa|journal=Journal of Geophysical Research|year=1993|volume=98|issue=B11|pages=19785–19793|doi=10.1029/93JB02218|bibcode = 1993JGR....9819785Z }}</ref> can be attained using WC anvils and a lanthanum chromite furnace. The apparatus is very bulky and cannot achieve pressures like those in the diamond anvil cell (below), but it can handle much larger samples that can be quenched and examined after the experiment.<ref>{{cite web
|+Table. 1 the fundamental frequency and overtone
  |title = Studying the Earth's formation: The multi-anvil press at work
|-
  |url = https://www.llnl.gov/str/Minarik.html
!Frequency
  |publisher= [[Lawrence Livermore National Laboratory]]
!Order
  |accessdate=29 September 2010
!
  |ref = {{harvid|LLNL|2010}}
!
}}</ref> Recently, [[sintering|sintered]] diamond anvils have been developed for this type of press that can reach pressures of 90 GPa (2700&nbsp;km depth).<ref>{{cite journal|last=Zhai|first=Shuangmeng|author2=Ito, Eiji|title=Recent advances of high-pressure generation in a multianvil apparatus using sintered diamond anvils|journal=Geoscience Frontiers|year=2011|volume=2|issue=1|pages=101–106|doi=10.1016/j.gsf.2010.09.005}}</ref>
|-
|''f'' = 440&nbsp;Hz
|''N'' = 1
|Fundamental frequency
|1st harmonic
|-
|f = 880&nbsp;Hz
|''N'' = 2
|1st overtone
|2nd harmonic
|-
|''f'' = 1320&nbsp;Hz
|''N'' = 3
|2nd overtone
|3rd harmonic
|-
|''f'' = 1760&nbsp;Hz
|''N'' = 4
|3rd overtone
|4th harmonic
|}
 
In [[musical theory]], pitch represents the perceived fundamental frequency of a sound. However the actual fundamental frequency may differ from the perceived fundamental frequency because of overtones.
 
==Short-time Fourier transform==
 
[[File:Chord.jpg|thumb|Fig.1 Waveform of the audio file "Chord.wav"{{where|date=October 2012}}]]
 
[[File:Garbor of Chord.png|thumb|Fig.2 Gabor transform of "Chord.wav"]]


===Diamond anvil cell===
[[File:Spectrogram of Chord.jpg|thumb|Fig. 3 Spectrogram of "Chord.wav"]]
[[Image:DiaAnvCell1.jpg|thumb|Schematics of the core of a diamond anvil cell. The diamond size is a few millimeters at most]]
The [[diamond anvil cell]] is a small table-top device for concentrating pressure. It can compress a small (sub-millimeter sized) piece of material to [[Orders of magnitude (pressure)|extreme pressure]]s, which can exceed 3,000,000 atmospheres (300 [[Pascal (unit)|gigapascals]]).<ref name=Hemley1998>{{Cite journal
|last = Hemley
|first = Russell J.
|last2 = Ashcroft
|first2 = Neil W.
|year = 1998
|title = The Revealing Role of Pressure in the Condensed Matter Sciences
|journal = [[Physics Today]]
|volume = 51
|pages = 26
|doi = 10.1063/1.882374
|bibcode = 1998PhT....51h..26H
|issue = 8 }}</ref> This is beyond the pressures at the center of the Earth. The concentration of pressure at the tip of the [[diamonds]] is possible because of their [[hardness]], while their [[transparency and translucency|transparency]] and high [[thermal conductivity]] allow a variety of probes can be used to examine the state of the sample.  The sample can be heated to thousands of degrees.


==Creating High Temperatures==
===Continuous STFT===
Achieve temperatures found within the interior of the earth is just as important to the study of Mineral Physics as creating to desired pressures. Several methods are used to reach these temperatures and measure them. Resistive heating is the most common and easiest to measure. The application of a voltage to a wire heats the wire and surrounding area. A large variety of heater designs are available including those that head the entire DAC body and those that fit inside the body to heat the sample chamber. Temperature below 700&nbsp;°C can be reached in air due to the oxidation of diamond above this temperature. With an argon atmosphere, higher temperatures up to 1700&nbsp;°C can be reached without damaging the diamonds. Resistive heaters have not achieved temperatures above 1000&nbsp;°C.
Laser-Heating is done in a diamond-anvil cell with Nd:YAG or CO2 lasers to achieve temperatures above 6000k. Optical spectroscopy is used to measure black body radiation from the sample to determine the temperature. Laser-heating is continuing to extend the temperature range that can be reached in diamond-anvil cell but suffers to significant drawbacks. First, temperatures below 1200k are difficult to measure using this method. Second, large temperature gradients exist in the sample because only the portion of sample hit by the laser are heated.


== Properties of materials ==
Short-time Fourier transform is a basic type of time–frequency analysis. If there is a continuous signal ''x''(''t''), we can compute the short-time Fourier transform by
:<math> \mathbf{STFT} \left \{ x(t) \right \} \equiv X(t, f) = \int_{-\infty}^{\infty} x(\tau) w(t-\tau) e^{-j 2 \pi f \tau} \, d \tau </math>
where ''w''(''t'') is a [[window function]]. When the ''w''(''t'') is a rectangular function, the transform is called Rec-STFT. When the ''w''(''t'') is a Gaussian function, the transform is called [[Gabor transform]].


=== Equations of state ===
===Discrete STFT===
To deduce the properties of minerals in the deep Earth, it is necessary to know how their [[density]] varies with [[pressure]] and [[temperature]]. Such a relation is called an [[equation of state]] (EOS). A simple example of an EOS that is predicted by the [[Debye model]] for harmonic lattice vibrations is the Mie-Grünheisen equation of state:<br />
:<math> \left(\frac{dP}{dT} \right) = \frac{\gamma_D}{V}C_V, </math>
where <math>C_V</math> is the [[heat capacity]] and <math>\gamma_D</math> is the Debye gamma. The latter is one of many Grünheisen parameters that play an important role in high-pressure physics. A more realistic EOS is the [[Birch–Murnaghan equation of state]].<ref name=Poirier>{{harvnb|Poirier|2000}}</ref>


=== Interpreting seismic velocities ===
However, normally the musical signal we have is not a continuous signal. It is sampled in a sampling frequency. Therefore, we can’t use the formula to compute the Rec-short-time Fourier transform. We change the original form to
Inversion of seismic data give profiles of seismic velocity as a function of depth. These must still be interpreted in terms of the properties of the minerals. A very useful heuristic was discovered by [[Francis Birch (geophysicist)|Francis Birch]]: plotting data for a large number of rocks, he found a linear relation of the [[compressional wave]] velocity <math>v_p</math> of rocks and minerals of a constant average [[atomic weight]] <math>\overline{M}</math> with density <math>\rho</math>:<ref name="JGR61">{{cite journal
:<math> X(n \, \Delta t,m \, \Delta f) = \sum_{p=n-Q}^{n+Q} x(p \, \Delta t) e^{-j 2 \pi p m \, \Delta t \, \Delta f} \, \Delta t</math>
|last=Birch
Let <math> t = n \, \Delta t </math>, <math>f = m \, \Delta f</math>, <math>\tau = p \, \Delta t </math> and <math> B = Q \, \Delta t</math>. There are some constraints of discrete short-time Fourier transform:
|first=F.
*<math>\Delta t \, \Delta f = \frac{1}{N},</math> where ''N'' is an integer.
|author-link = Francis Birch (geophysicist)
*<math>N \ge 2Q+1</math>
|year=1961
*<math>\Delta < \frac{1}{2f_\max}</math> , where <math>f_\max</math> is the highest frequency in the signal.
|title=The velocity of compressional waves in rocks to 10 kilobars. Part 2
|journal=[[Journal of Geophysical Research]]
|volume=66 |pages=2199–2224
|doi=10.1029/JZ066i007p02199
|bibcode = 1961JGR....66.2199B
|issue=7 }}</ref><ref name="GJRAS61">{{cite journal
|last=Birch
|first=F.
|author-link = Francis Birch (geophysicist)
|year=1961
|title=Composition of the Earth's mantle
|journal=[[Geophysical Journal of the Royal Astronomical Society]]
|volume=4 |pages=295–311
|doi=10.1111/j.1365-246X.1961.tb06821.x
|bibcode = 1961GeoJI...4..295B }}</ref><br />
:<math> v_p = a \overline{M} + b \rho </math>.
This makes it possible to extrapolate known velocities for minerals at the surface to predict velocities deeper in the Earth.


=== Other physical properties ===
==STFT example==
* [[Viscosity]]
* [[Creep (deformation)]]
* [[Melting]]
* [[Electrical conduction]] and other transport properties


=== Methods of Crystal Interrogation ===
Fig.1 shows the waveform of a piano music audio file with 44100&nbsp;Hz sampling frequency. And Fig.2 shows the result of short-time Fourier transform (we use Gabor transform here) of the audio file. We can see from the time–frequency plot, from ''t''&nbsp;=&nbsp;0 to 0.5 second, there is a chord with three notes, and the chord changed at ''t''&nbsp;=&nbsp;0.5, and then changed again at&nbsp;''t''&nbsp;=&nbsp;1. The fundamental frequency of each note in each chord is show in the time–frequency plot.


There are a number of experimental procedures designed to extract information from both single and powdered crystals. Some techniques can be used in a [[diamond anvil cell]](DAC) or a multi anvil press(MAP).  Some techniques are summarized in the following table.
==Spectrogram==
{| class="wikitable"
 
|-
Figure 3 shows the [[spectrogram]] of the audio file shows in Figure 1. Spectrogram is the square of STFT, time-varying spectral representation. The spectrogram of a signal ''s''(''t'') can be estimated by computing the squared [[magnitude (mathematics)|magnitude]] of the STFT of the signal ''s''(''t''), as shown below:
! Technique !! Anvil Type !! Sample Type !! Information Extracted !! Limitations
 
|-
: <math> \mathbf {spectrogram} (t,f) = \left| \mathbf{STFT} (t,f) \right|^2 </math>
| [[X-ray diffraction|X-ray Diffraction(XRD)]] || DAC or MAP|| Powder or Single Crystal|| [[Bravais lattice|cell parameters]] || 
 
|-
Although the spectrogram is profoundly useful, it still has one drawback. It displays frequencies on a uniform scale. However, musical scales are based on a logarithmic scale for frequencies. Therefore, we should describe the frequency in logarithmic scale related to human hearing.
| [[Electron microscope|Electron Microscopoy]] || Neither || Powder or Single Crystal || [[Bravais lattice|Symmetry Group]] || Surface Measurements Only
 
|-
==Wigner distribution function==
| [[Neutron diffraction|Neutron Diffraction]] || Neither || Powder || [[Bravais lattice|cell parameters]] || Large Sample needed
 
|-
The [[Wigner distribution function]] can also be used to analyze music signal.  The advantage of Wigner distribution function is the high clarity. However, it needs high calculation and has cross-term problem, so it's more suitable to analyze signal without more than one frequency at the same time.
| [[Infrared spectroscopy]] || DAC || Powder, Single Crystal or Solution || Chemical Composition || Not all materials are IR active
 
|-
===Formula===
| [[Raman spectroscopy|Raman Spectroscopy]] || DAC || Powder, Single Crystal or Solution || Chemical Composition || Not all materials are Raman active
 
|-
The Wigner distribution function <math>W_x(t,f)</math> is:
| [[Brillouin Scattering]] || DAC || Single Crystal || [[Elastic modulus|Elastic Moduli]] || Need optically thin sample
 
|-
:<math> \mathbf W_x(t,f) = \int_ {-\infty}^\infty x(t+\tau/2)x^*(t-\tau/2) e^{-j2\pi\tau\,f} \,d \tau, </math>
| Ultrasonic Interferometry<ref>http://serc.carleton.edu/NAGTWorkshops/mineralogy/mineral_physics/ultrasonic.html</ref> || DAC or MAP || Single Crystal || [[Elastic modulus|Elastic Moduli]] ||
|}


===First Principles Calculations===
where ''x''(''t'') is the signal, and ''x''*(''t'') is the conjugate of the signal.
{{main|Prediction of crystal properties by numerical simulation}}
Using quantum mechanical numerical techniques, it is possible to achieve very accurate predictions of crystal's properties including structure, thermodynamic stability, elastic properties and transport properties.  The limit of such calculations tends to be computing power, as computation run times of weeks or even months are not uncommon.


== References ==
==See also==
{{Reflist|2}}


== Further reading ==
*[[Musical acoustics]]
{{Refbegin}}
*[[Harmonic pitch class profiles]] (HPCP)
*{{cite book
  |last = Poirier
  |first = Jean-Paul
  |title = Introduction to the Physics of the Earth's Interior
  |series = Cambridge Topics in Mineral Physics & Chemistry
  |publisher = [[Cambridge University Press]]
  |year = 2000
  |isbn = 0-521-66313-X
}}
{{Refend}}


== External links ==
==Sources==
*{{cite web|url=http://serc.carleton.edu/NAGTWorkshops/mineralogy/mineral_physics.html |title=Teaching Mineral Physics Across the Curriculum |work=On the cutting edge - professional development for geoscience faculty |accessdate=21 May 2012}}


{{Geophysics navbox}}
* Joan Serra, Emilia Gomez, Perfecto Herrera, and [[Xavier Serra]], "Chroma Binary Similarity and Local Alignment Applied to Cover Song Identification," August, 2008
* William J. Pielemeier, Gregory H. Wakefield, and Mary H. Simoni, "Time–frequency Analysis of Musical Signals," September,1996
* Jeremy F. Alm and James S. Walker, "Time–Frequency Analysis of Musical Instruments," 2002
* Monika Dorfler, "What Time–Frequency Analysis Can Do To Music Signals," April,2004
* EnShuo Tsau, Namgook Cho and C.-C. Jay Kuo, "Fundamental Frequency Estimation For Music Signals with Modified [[Hilbert–Huang transform]]" IEEE International Conference on Multimedia and Expo, 2009.


[[Category:Solid mechanics]]
{{DEFAULTSORT:Time-frequency analysis for music signals}}
[[Category:Geodynamics]]
[[Category:Musical analysis]]
[[Category:Mineralogy]]
[[Category:Time–frequency analysis|Musical signal]]

Revision as of 11:11, 18 August 2014

Template:No footnotes

Time–frequency analysis for music signals is one of the applications of time–frequency analysis. Musical sound can be more complicated than human vocal sound, occupying a wider band of frequency. Music signals are time-varying signals; while the classic Fourier transform is not sufficient to analyze them, time–frequency analysis is an efficient tool for such use. Time–frequency analysis is extended from the classic Fourier approach. Short-time Fourier transform (STFT), Gabor transform (GT) and Wigner distribution function (WDF) are famous time–frequency methods, useful for analyzing music signals such as notes played on a piano, a flute or a guitar.

Knowledge about music signal

Music is a type of sound that has some stable frequencies in a time period. Music can be produced by several methods. For example, the sound of a piano is produced by striking strings, and the sound of a violin is produced by bowing. All musical sounds have their fundamental frequency and overtones. Fundamental frequency is the lowest frequency in harmonic series. In a periodic signal, the fundamental frequency is the inverse of the period length. Overtones are integer multiples of the fundamental frequency.

Table. 1 the fundamental frequency and overtone
Frequency Order
f = 440 Hz N = 1 Fundamental frequency 1st harmonic
f = 880 Hz N = 2 1st overtone 2nd harmonic
f = 1320 Hz N = 3 2nd overtone 3rd harmonic
f = 1760 Hz N = 4 3rd overtone 4th harmonic

In musical theory, pitch represents the perceived fundamental frequency of a sound. However the actual fundamental frequency may differ from the perceived fundamental frequency because of overtones.

Short-time Fourier transform

Fig.1 Waveform of the audio file "Chord.wav"Template:Where
Fig.2 Gabor transform of "Chord.wav"
Fig. 3 Spectrogram of "Chord.wav"

Continuous STFT

Short-time Fourier transform is a basic type of time–frequency analysis. If there is a continuous signal x(t), we can compute the short-time Fourier transform by

where w(t) is a window function. When the w(t) is a rectangular function, the transform is called Rec-STFT. When the w(t) is a Gaussian function, the transform is called Gabor transform.

Discrete STFT

However, normally the musical signal we have is not a continuous signal. It is sampled in a sampling frequency. Therefore, we can’t use the formula to compute the Rec-short-time Fourier transform. We change the original form to

Let , , and . There are some constraints of discrete short-time Fourier transform:

STFT example

Fig.1 shows the waveform of a piano music audio file with 44100 Hz sampling frequency. And Fig.2 shows the result of short-time Fourier transform (we use Gabor transform here) of the audio file. We can see from the time–frequency plot, from t = 0 to 0.5 second, there is a chord with three notes, and the chord changed at t = 0.5, and then changed again at t = 1. The fundamental frequency of each note in each chord is show in the time–frequency plot.

Spectrogram

Figure 3 shows the spectrogram of the audio file shows in Figure 1. Spectrogram is the square of STFT, time-varying spectral representation. The spectrogram of a signal s(t) can be estimated by computing the squared magnitude of the STFT of the signal s(t), as shown below:

Although the spectrogram is profoundly useful, it still has one drawback. It displays frequencies on a uniform scale. However, musical scales are based on a logarithmic scale for frequencies. Therefore, we should describe the frequency in logarithmic scale related to human hearing.

Wigner distribution function

The Wigner distribution function can also be used to analyze music signal. The advantage of Wigner distribution function is the high clarity. However, it needs high calculation and has cross-term problem, so it's more suitable to analyze signal without more than one frequency at the same time.

Formula

The Wigner distribution function is:

where x(t) is the signal, and x*(t) is the conjugate of the signal.

See also

Sources

  • Joan Serra, Emilia Gomez, Perfecto Herrera, and Xavier Serra, "Chroma Binary Similarity and Local Alignment Applied to Cover Song Identification," August, 2008
  • William J. Pielemeier, Gregory H. Wakefield, and Mary H. Simoni, "Time–frequency Analysis of Musical Signals," September,1996
  • Jeremy F. Alm and James S. Walker, "Time–Frequency Analysis of Musical Instruments," 2002
  • Monika Dorfler, "What Time–Frequency Analysis Can Do To Music Signals," April,2004
  • EnShuo Tsau, Namgook Cho and C.-C. Jay Kuo, "Fundamental Frequency Estimation For Music Signals with Modified Hilbert–Huang transform" IEEE International Conference on Multimedia and Expo, 2009.