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[[File:Pyrosensor.jpg|thumb|Pyroelectric sensor]]
'''Pyroelectricity''' (from the Greek ''pyr'', fire, and [[electricity]]) is the ability of certain materials to generate a temporary [[voltage]]  when they are heated or cooled.<ref name=Webster/> The change in temperature modifies the positions of the atoms slightly  within the [[crystal structure]], such that the [[polarization (electrostatics)|polarization]] of the material changes. This polarization change gives rise to a voltage across the crystal. If the temperature stays constant at its new value, the pyroelectric voltage gradually disappears due to [[Leakage (electronics)|leakage current]] (the leakage can be due to electrons moving through the crystal, ions moving through the air, current leaking through a [[voltmeter]] attached across the crystal, etc.).<ref name=Webster>{{cite book | url = http://books.google.com/books?id=VXQdq0B3tnUC&pg=SA32-PA113 | title = The measurement, instrumentation, and sensors handbook | pages =32–113 | isbn = 978-0-8493-8347-2 | author1 = Webster, John G | year = 1999}}</ref><ref>In this article, the term "voltage" is used in the everyday sense, i.e. what a [[voltmeter]] measures. This is actually the [[electrochemical potential]], not the [[electrostatic potential]] ([[Galvani potential]]).</ref>
 
Pyroelectricity should not be confused with [[thermoelectricity]]: In a typical demonstration of pyroelectricity, the whole crystal is changed from one temperature to another, and the result is a temporary voltage across the crystal. In a typical demonstration of thermoelectricity, one part of the device is kept at one temperature and the other part at a different temperature, and the result is a ''permanent'' voltage across the device as long as there is a temperature difference.
 
== Explanation ==
Pyroelectricity can be visualized as one side of a triangle, where each corner represents energy states in the crystal: [[kinetic energy|kinetic]], [[electrical energy|electrical]] and [[thermal energy]]. The side between electrical and thermal corners represents the pyroelectric effect and produces no [[kinetic energy]]. The side between kinetic and electrical corners represents the [[piezoelectric effect]] and produces no [[heat]].
 
Although artificial pyroelectric materials have been engineered, the effect was first discovered in minerals such as [[tourmaline]]. The pyroelectric effect is also present in both [[bone]] and [[tendon]].
 
Pyroelectric charge in [[mineral]]s develops on the opposite faces of asymmetric crystals. The direction in which the propagation of the charge tends toward is usually constant throughout a pyroelectric material, but in some materials this direction can be changed by a nearby electric field.  These materials are said to exhibit [[ferroelectricity]].  All pyroelectric materials are also [[piezoelectricity|piezoelectric]], the two properties being closely related. However, note that some piezoelectric materials have a crystal symmetry that does not allow pyroelectricity.
 
Very small changes in temperature can produce an electric potential due to a materials' pyroelectricity. [[Passive infrared sensor]]s are often designed around pyroelectric materials, as the heat of a human or animal from several feet away is enough to generate a difference in charge.
 
== History ==
The first reference to the pyroelectric effect is in writings by [[Theophrastus]] in 314 BC, who noted that ''lyngourion'' could attract sawdust or bits of straw.<ref>Earle R. Caley and John F.C. Richards, ''Theophrastus:  On Stones'' (Columbus, Ohio:  Ohio State University, 1956), page 51, paragraph 28 of the original text:  "It [''smaragdos''] is remarkable in its powers, and so is the ''lyngourion'' [i.e., lynx-urine stone] … .  It has the power of attraction, just as amber has, and some say that it not only attracts straws and bits of wood, but also copper and iron, if the pieces are thin, as Diokles used to explain."</ref> [[Tourmaline]]'s properties were rediscovered in 1707 by [[Johann Georg Schmidt (scientist)|Johann Georg Schmidt]], who noted that the stone attracted only hot ashes, not cold ones.<ref>Johann Georg Schmidt, ''Curiöse Speculationes bey Schalflosen Nächten'' [Curious Speculations During Sleepless Nights] (Chemnitz and Leipzig (Germany): Conrad Stössen, 1707), pages 269-270. An English translation of the relevant passage appears in: Sidney B. Lang, ''Sourcebook of Pyroelectricity'', vol. 2 (New York, New York:  Gordon and Breach, 1974), [http://books.google.com/books?id=pqjNNDYdBPkC&pg=PA96#v=onepage&q&f=false page 96].</ref>  In 1717  [[Louis Lemery]] noticed, as Schmidt had, that small scraps of non-conducting material were first attracted to tourmaline, but then repelled by it once they contacted the stone.<ref>"Diverse observations de la physique generale," ''Histoire de l'Académie des Sciences'' (1717); [http://gallica.bnf.fr/ark:/12148/bpt6k5426516z/f16.image see pages 7-8].</ref>  In 1747 [[Linnaeus]] first related the phenomenon to electricity (he called tourmaline ''Lapidem Electricum'', "the electric stone"),<ref>Carl von Linné ("Linnaeus"), ''Flora Zeylanica: Sistens Plantas Indicas Zeylonae Insulae'' [The Flora of Ceylon: consisting of Indian plants of the island of Ceylon] (Stockholm ("Holmiae"), Sweden:  Laurentii Salvii, 1747), [http://books.google.com/books?id=f0Y-AAAAcAAJ&pg=PA8#v=onepage&q&f=false page 8]. A translation of the relevant passage appears in Lang (1974), page 103.</ref> although this was not proven until 1756 by [[Franz Ulrich Theodor Aepinus]].<ref>Aepinus (1756) "Memoire concernant quelques nouvelles experiences électriques remarquables" [Memoir concerning some remarkable new electrical experiments], ''Histoire de l'Académie royale des sciences et des belles lettres'' (Berlin), vol. 12, [http://books.google.com/books?id=mZgDAAAAMAAJ&pg=PA105#v=onepage&q&f=false pages 105-121].</ref> {{Citation needed|date=January 2012}}
 
Research in pyroelectricity became more sophisticated in the 19th century.  In 1824 [[David Brewster|Sir David Brewster]] gave the effect the name it has today.<ref>{{cite journal| url = http://books.google.de/books?id=dkQEAAAAYAAJ&pg=PA208| pages = 208–215 | first = David | last = Brewster | title = Observations of the pyro-electricity of minerals |journal = The Edinburgh Journal of Science | volume = 1 | year =  1824 }}</ref> Both [[William Thomson, 1st Baron Kelvin|William Thomson]] in 1878<ref>William Thomson (1878) "On the thermoelastic, thermomagnetic and pyroelectric properties of matter," ''Philosophical Magazine'', series 5, vol. 5, [http://books.google.com/books?id=A5YOAAAAIAAJ&pg=PA4#v=onepage&q&f=false pages 4 - 26].</ref> and [[Woldemar Voigt]] in 1897<ref>W. Voigt (1897) "Versuch zur Bestimmung des wahren specifischen electrischen Momentes eines Turmalins"  (Experiment to determine the true specific electric moment of a tourmaline), ''Annalen der Physik'', vol. 60, [http://books.google.com/books?id=iX0EAAAAYAAJ&pg=PA368#v=onepage&q&f=false pages 368 - 375].</ref> helped develop a theory for the processes behind pyroelectricity. [[Pierre Curie]] and his brother, [[Jacques Curie]], studied pyroelectricity in the 1880s, leading to their discovery of some of the mechanisms behind piezoelectricity. {{Citation needed|date=January 2012}}
 
== The pyroelectric crystal classes and piezoelectricity ==
All [[crystal structures]] can be divided into 32 [[Crystal_system#Crystal classes|crystal classes]], according to the number of [[Rotational symmetry|rotational axes]] and [[mirror plane|reflection planes]] they exhibit that leave the crystal structure unchanged. Of the thirty-two crystal classes, twenty-one are non-centrosymmetric (not having a [[Fixed points of isometry groups in Euclidean space|centre of symmetry]]). Of these twenty-one, twenty exhibit direct [[piezoelectricity]], the remaining one being the cubic class 432. Ten of these twenty piezoelectric classes are polar, i.e., they possess a spontaneous polarization, having a dipole in their unit cell, and exhibit pyroelectricity. If this dipole can be reversed by the application of an electric field, the material is said to be [[ferroelectric]]. Any dielectric material develops a dielectric [[polarization (electrostatics)]] when an electric field is applied, but a substance which has such a natural charge separation even in the absence of a field is called a polar material. Whether or not a material is polar is determined solely by its crystal structure.  Only 10 of the 32 point groups are polar. All [[polar crystals]] are pyroelectric, so the 10 [[polar crystal classes]] are sometimes referred to as the pyroelectric classes.
 
Piezoelectric crystal classes: 1, 2, m, 222, mm2, 4, -4, 422, 4mm, -42m, 3, 32, 3m, 6, -6, 622, 6mm, -62m, 23, -43m
 
Pyroelectric: 1, 2, m, mm2, 3, 3m, 4, 4mm, 6, 6mm
 
The property of pyroelectricity is the measured change in net polarization (a vector) proportional to a change in temperature.  The total pyroelectric coefficient measured at constant stress is the sum of the pyroelectric coefficients at constant strain (primary pyroelectric effect) and the piezoelectric contribution from thermal expansion (secondary pyroelectric effect). Under normal circumstances,  even polar materials do not display a net dipole moment.  As a consequence there are no electric dipole equivalents of bar magnets because the intrinsic dipole moment is neutralized by "free" electric charge that builds up on the surface by internal conduction or from the ambient atmosphere.  Polar crystals only reveal their nature when perturbed in some fashion that momentarily upsets the balance with the compensating surface charge.
 
== Recent developments ==
Progress has been made in creating artificial pyroelectric materials, usually in the form of a thin film, out of [[gallium nitride]] ([[Gallium|Ga]][[Nitrogen|N]]), [[caesium nitrate]] ([[Caesium|Cs]][[Nitrogen|N]][[Oxygen|O]]<sub>3</sub>), [[polyvinyl fluoride]]s, derivatives of [[phenylpyridine]], and [[cobalt]] [[phthalocyanine]]. (See [[pyroelectric crystal]]s.) [[Lithium tantalate]] ([[Lithium|Li]][[Tantalum|Ta]][[Oxygen|O]]<sub>3</sub>) is a crystal exhibiting both [[piezoelectric]] and pyroelectric properties, which has been used to create small-scale [[nuclear fusion]] ("[[pyroelectric fusion]]").<ref name="NaranjoGimzewski2005">{{cite journal|last1=Naranjo|first1=B.|last2=Gimzewski|first2=J.K.|last3=Putterman|first3=S.|title=Observation of nuclear fusion driven by a pyroelectric crystal|journal=Nature|volume=434|issue=7037|year=2005|pages=1115–1117|issn=0028-0836|doi=10.1038/nature03575|url=http://www.nature.com/nature/journal/v434/n7037/suppinfo/nature03575.html}}</ref>
 
== Mathematical description ==
The pyroelectric coefficient may be described as the change in the spontaneous polarization vector with temperature:<ref>Damjanovic, Dragan, 1998, Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics, ''Rep. Prog. Phys.'' 61, 1267–1324.</ref>
:<math>
p_i = \frac{\partial P_{S,i}} {\partial T}
</math>
where ''p<sub>i</sub>'' (Cm<sup>−2</sup>K<sup>−1</sup>)
is the vector for the pyroelectric coefficient.
 
== Power generation ==
A pyroelectric can be repeatedly heated and cooled (analogously to a [[heat engine]]) to generate usable electrical power. One group calculated that a pyroelectric in an [[Ericsson cycle]] could reach 50% of [[Carnot efficiency]],<ref>{{cite journal | last1 = Sebald | first1 = Gael | last2 = Pruvost | first2 = Sebastien | last3 = Guyomar | first3 = Daniel | title = Energy harvesting based on Ericsson pyroelectric cycles in a relaxor ferroelectric ceramic | journal = Smart Materials and Structures | volume = 17 | pages = 015012 | year = 2008 | doi = 10.1088/0964-1726/17/01/015012 |bibcode = 2008SMaS...17a5012S |url=http://www.ikhebeenvraag.be/mediastorage/FSDocument/135/Pyroelectric+energy+harvesting.pdf}}</ref><ref>{{cite journal | last1 = Sebald | first1 = Gael | last2 = Guyomar | first2 = Daniel | last3 = Agbossou | first3 = Amen | title = On thermoelectric and pyroelectric energy harvesting | journal = Smart Materials and Structures | volume = 18 | pages = 125006 | year = 2009 | doi = 10.1088/0964-1726/18/12/125006 |bibcode = 2009SMaS...18l5006S }}</ref> while a different study found a material that could in theory reach 84-92% of Carnot efficiency<ref>{{cite journal | last1 = Olsen | first1 = Randall B. | last2 = Evans | first2 = Diane | title = Pyroelectric energy conversion: Hysteresis loss and temperature sensitivity of a ferroelectric material | journal = Journal of Applied Physics | volume = 54 | pages = 5941 | year = 1983 | doi = 10.1063/1.331769|bibcode = 1983JAP....54.5941O }}</ref> (these efficiency values are for the pyroelectric itself, ignoring losses from heating and cooling the [[thin film|substrate]], other heat-transfer losses, and all other losses elsewhere in the system). Possible advantages of pyroelectric generators for generating electricity (as compared to the conventional [[heat engine]] plus [[electrical generator]]) include potentially lower [[operating temperature]]s, less bulky equipment, and fewer moving parts.<ref>{{cite journal | last1 = Kouchachvili | first1 = L | last2 = Ikura | first2 = M | title = Pyroelectric conversion—Effects of P(VDF–TrFE) preconditioning on power conversion | journal = Journal of Electrostatics | volume = 65 | pages = 182 | year = 2007 | doi = 10.1016/j.elstat.2006.07.014}}</ref> Although a few patents have been filed for such a device,<ref>For example: [http://www.freepatentsonline.com/4647836.html US Patent 4647836], [http://www.freepatentsonline.com/6528898.html US Patent 6528898], [http://www.freepatentsonline.com/5644184.html US Patent 5644184]</ref> it does not appear to be anywhere close to commercialization yet.
 
== See also ==
*[[Pyroelectric crystal]]
*[[Pyroelectric fusion]]
*The opposite effect is called [[electrocaloric effect]]
*[[Thermoelectricity]]
*[[Kelvin probe force microscope]]
 
== References ==
{{reflist}}
* Gautschi, Gustav, 2002, ''Piezoelectric Sensorics'', Springer, ISBN 3-540-42259-5 [http://books.google.com/books?id=-nYFSLcmc-cC&pg=PA6&ots=WB87B6JdvU&dq=Ha%C3%BCy+piezoelectricity&sig=-1-Z2258zsX0MOLG253kqwm3_Ns#PPA6,M1]
 
== External links ==
*[http://www.infratec.de/en/sensor-division/sensor-division-knowledge/faq.html Substantial explanations of pyroelectric detector operation]
*[http://www.dias-infrared.de/pdf/basics_eng.pdf Pyroelectric Infrared Detectors] DIAS Infrared
*[http://www.doitpoms.ac.uk/tlplib/pyroelectricity/index.php DoITPoMS Teaching and Learning Package- "Pyroelectric Materials"]
 
<!--Categories-->
[[Category:Thermodynamics]]
[[Category:Electrical phenomena]]
[[Category:Energy conversion]]

Revision as of 04:43, 29 January 2014

Pyroelectric sensor

Pyroelectricity (from the Greek pyr, fire, and electricity) is the ability of certain materials to generate a temporary voltage when they are heated or cooled.[1] The change in temperature modifies the positions of the atoms slightly within the crystal structure, such that the polarization of the material changes. This polarization change gives rise to a voltage across the crystal. If the temperature stays constant at its new value, the pyroelectric voltage gradually disappears due to leakage current (the leakage can be due to electrons moving through the crystal, ions moving through the air, current leaking through a voltmeter attached across the crystal, etc.).[1][2]

Pyroelectricity should not be confused with thermoelectricity: In a typical demonstration of pyroelectricity, the whole crystal is changed from one temperature to another, and the result is a temporary voltage across the crystal. In a typical demonstration of thermoelectricity, one part of the device is kept at one temperature and the other part at a different temperature, and the result is a permanent voltage across the device as long as there is a temperature difference.

Explanation

Pyroelectricity can be visualized as one side of a triangle, where each corner represents energy states in the crystal: kinetic, electrical and thermal energy. The side between electrical and thermal corners represents the pyroelectric effect and produces no kinetic energy. The side between kinetic and electrical corners represents the piezoelectric effect and produces no heat.

Although artificial pyroelectric materials have been engineered, the effect was first discovered in minerals such as tourmaline. The pyroelectric effect is also present in both bone and tendon.

Pyroelectric charge in minerals develops on the opposite faces of asymmetric crystals. The direction in which the propagation of the charge tends toward is usually constant throughout a pyroelectric material, but in some materials this direction can be changed by a nearby electric field. These materials are said to exhibit ferroelectricity. All pyroelectric materials are also piezoelectric, the two properties being closely related. However, note that some piezoelectric materials have a crystal symmetry that does not allow pyroelectricity.

Very small changes in temperature can produce an electric potential due to a materials' pyroelectricity. Passive infrared sensors are often designed around pyroelectric materials, as the heat of a human or animal from several feet away is enough to generate a difference in charge.

History

The first reference to the pyroelectric effect is in writings by Theophrastus in 314 BC, who noted that lyngourion could attract sawdust or bits of straw.[3] Tourmaline's properties were rediscovered in 1707 by Johann Georg Schmidt, who noted that the stone attracted only hot ashes, not cold ones.[4] In 1717 Louis Lemery noticed, as Schmidt had, that small scraps of non-conducting material were first attracted to tourmaline, but then repelled by it once they contacted the stone.[5] In 1747 Linnaeus first related the phenomenon to electricity (he called tourmaline Lapidem Electricum, "the electric stone"),[6] although this was not proven until 1756 by Franz Ulrich Theodor Aepinus.[7] Potter or Ceramic Artist Truman Bedell from Rexton, has interests which include ceramics, best property developers in singapore developers in singapore and scrabble. Was especially enthused after visiting Alejandro de Humboldt National Park.

Research in pyroelectricity became more sophisticated in the 19th century. In 1824 Sir David Brewster gave the effect the name it has today.[8] Both William Thomson in 1878[9] and Woldemar Voigt in 1897[10] helped develop a theory for the processes behind pyroelectricity. Pierre Curie and his brother, Jacques Curie, studied pyroelectricity in the 1880s, leading to their discovery of some of the mechanisms behind piezoelectricity. Potter or Ceramic Artist Truman Bedell from Rexton, has interests which include ceramics, best property developers in singapore developers in singapore and scrabble. Was especially enthused after visiting Alejandro de Humboldt National Park.

The pyroelectric crystal classes and piezoelectricity

All crystal structures can be divided into 32 crystal classes, according to the number of rotational axes and reflection planes they exhibit that leave the crystal structure unchanged. Of the thirty-two crystal classes, twenty-one are non-centrosymmetric (not having a centre of symmetry). Of these twenty-one, twenty exhibit direct piezoelectricity, the remaining one being the cubic class 432. Ten of these twenty piezoelectric classes are polar, i.e., they possess a spontaneous polarization, having a dipole in their unit cell, and exhibit pyroelectricity. If this dipole can be reversed by the application of an electric field, the material is said to be ferroelectric. Any dielectric material develops a dielectric polarization (electrostatics) when an electric field is applied, but a substance which has such a natural charge separation even in the absence of a field is called a polar material. Whether or not a material is polar is determined solely by its crystal structure. Only 10 of the 32 point groups are polar. All polar crystals are pyroelectric, so the 10 polar crystal classes are sometimes referred to as the pyroelectric classes.

Piezoelectric crystal classes: 1, 2, m, 222, mm2, 4, -4, 422, 4mm, -42m, 3, 32, 3m, 6, -6, 622, 6mm, -62m, 23, -43m

Pyroelectric: 1, 2, m, mm2, 3, 3m, 4, 4mm, 6, 6mm

The property of pyroelectricity is the measured change in net polarization (a vector) proportional to a change in temperature. The total pyroelectric coefficient measured at constant stress is the sum of the pyroelectric coefficients at constant strain (primary pyroelectric effect) and the piezoelectric contribution from thermal expansion (secondary pyroelectric effect). Under normal circumstances, even polar materials do not display a net dipole moment. As a consequence there are no electric dipole equivalents of bar magnets because the intrinsic dipole moment is neutralized by "free" electric charge that builds up on the surface by internal conduction or from the ambient atmosphere. Polar crystals only reveal their nature when perturbed in some fashion that momentarily upsets the balance with the compensating surface charge.

Recent developments

Progress has been made in creating artificial pyroelectric materials, usually in the form of a thin film, out of gallium nitride (GaN), caesium nitrate (CsNO3), polyvinyl fluorides, derivatives of phenylpyridine, and cobalt phthalocyanine. (See pyroelectric crystals.) Lithium tantalate (LiTaO3) is a crystal exhibiting both piezoelectric and pyroelectric properties, which has been used to create small-scale nuclear fusion ("pyroelectric fusion").[11]

Mathematical description

The pyroelectric coefficient may be described as the change in the spontaneous polarization vector with temperature:[12]

where pi (Cm−2K−1) is the vector for the pyroelectric coefficient.

Power generation

A pyroelectric can be repeatedly heated and cooled (analogously to a heat engine) to generate usable electrical power. One group calculated that a pyroelectric in an Ericsson cycle could reach 50% of Carnot efficiency,[13][14] while a different study found a material that could in theory reach 84-92% of Carnot efficiency[15] (these efficiency values are for the pyroelectric itself, ignoring losses from heating and cooling the substrate, other heat-transfer losses, and all other losses elsewhere in the system). Possible advantages of pyroelectric generators for generating electricity (as compared to the conventional heat engine plus electrical generator) include potentially lower operating temperatures, less bulky equipment, and fewer moving parts.[16] Although a few patents have been filed for such a device,[17] it does not appear to be anywhere close to commercialization yet.

See also

References

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  • Gautschi, Gustav, 2002, Piezoelectric Sensorics, Springer, ISBN 3-540-42259-5 [1]

External links

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  2. In this article, the term "voltage" is used in the everyday sense, i.e. what a voltmeter measures. This is actually the electrochemical potential, not the electrostatic potential (Galvani potential).
  3. Earle R. Caley and John F.C. Richards, Theophrastus: On Stones (Columbus, Ohio: Ohio State University, 1956), page 51, paragraph 28 of the original text: "It [smaragdos] is remarkable in its powers, and so is the lyngourion [i.e., lynx-urine stone] … . It has the power of attraction, just as amber has, and some say that it not only attracts straws and bits of wood, but also copper and iron, if the pieces are thin, as Diokles used to explain."
  4. Johann Georg Schmidt, Curiöse Speculationes bey Schalflosen Nächten [Curious Speculations During Sleepless Nights] (Chemnitz and Leipzig (Germany): Conrad Stössen, 1707), pages 269-270. An English translation of the relevant passage appears in: Sidney B. Lang, Sourcebook of Pyroelectricity, vol. 2 (New York, New York: Gordon and Breach, 1974), page 96.
  5. "Diverse observations de la physique generale," Histoire de l'Académie des Sciences (1717); see pages 7-8.
  6. Carl von Linné ("Linnaeus"), Flora Zeylanica: Sistens Plantas Indicas Zeylonae Insulae [The Flora of Ceylon: consisting of Indian plants of the island of Ceylon] (Stockholm ("Holmiae"), Sweden: Laurentii Salvii, 1747), page 8. A translation of the relevant passage appears in Lang (1974), page 103.
  7. Aepinus (1756) "Memoire concernant quelques nouvelles experiences électriques remarquables" [Memoir concerning some remarkable new electrical experiments], Histoire de l'Académie royale des sciences et des belles lettres (Berlin), vol. 12, pages 105-121.
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    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  9. William Thomson (1878) "On the thermoelastic, thermomagnetic and pyroelectric properties of matter," Philosophical Magazine, series 5, vol. 5, pages 4 - 26.
  10. W. Voigt (1897) "Versuch zur Bestimmung des wahren specifischen electrischen Momentes eines Turmalins" (Experiment to determine the true specific electric moment of a tourmaline), Annalen der Physik, vol. 60, pages 368 - 375.
  11. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  12. Damjanovic, Dragan, 1998, Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics, Rep. Prog. Phys. 61, 1267–1324.
  13. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  14. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  15. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  16. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  17. For example: US Patent 4647836, US Patent 6528898, US Patent 5644184