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The '''mass-action ratio''',<ref>B. Hess and K. Brand. (1965). Enzymes and metabolite profiles. In Control of energy metabolism. III. Ed. B. Chance, R. K. Estabrook and J. R. Williamson. New York: Academic Press.</ref> often denoted by <math>\Gamma</math>, is the ratio of product concentrations to reactant concentrations at one given time which may be at equilibrium or not.
 
<math>\Gamma = \frac{ P_1 P_2 \ldots}{ S_1 S_2 \ldots} </math>
 
If the product and reactant concentrations are at equilibrium then the mass-action ratio will equal the equilibrium constant. At equilibrium:
 
<math>\Gamma = K_{eq}</math>
 
The ratio of the mass-action ratio to the equilibrium constant is often called the disequilibrium ratio, denoted by the symbol <math>\rho</math>.
 
<math>\rho = \frac{\Gamma}{K_{eq}}</math>
 
At equilibrium <math>\rho = 1</math>. When the reaction is out of equilibrium <math>\rho < 1</math> but always greater than zero.
 
==References==
{{Reflist}}
 
==Other sources==
*[[Peter Atkins|Atkins, P.W.]] (1978). ''Physical Chemistry'' [[Oxford University Press]] ISBN 0-7167-3539-3
*Trevor Palmer (2001) Enzymes: biochemistry, biotechnology and clinical chemistry Chichester Horwood Publishing ISBN 1-898563-78-0
 
{{DEFAULTSORT:Mass-Action Ratio}}
[[Category:Physical chemistry]]

Revision as of 03:06, 11 February 2014



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