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[[File:Melting icecubes.gif|thumb|Ice melting]]
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{{Redirect|Molten|the Japanese company|Molten Corporation|other uses|Molton (disambiguation)|and|Moulton (disambiguation)}}
 
'''Melting''', or '''fusion''', is a physical process that results in the [[phase transition]] of a substance from a [[solid]] to a [[liquid]]. The [[internal energy]] of a substance is increased, typically by the application of heat or pressure, resulting in a rise of its temperature to the [[melting point]], at which the ordering of ionic or molecular entities in the solid breaks down to a less ordered state and the solid liquefies. An object that has melted completely is ''molten''. Substances in the molten state generally have reduced viscosity with elevated temperature; an exception to this maxim is the element [[sulfur]], whose viscosity increases to a point due to [[polymerization]] and then decreases with higher temperatures in its molten state.<ref>C.Michael Hogan (2011) ''Sulfur'', Encyclopedia of Earth, eds. A.Jorgensen and C.J.Cleveland, National Council for Science and the environment, Washington DC</ref>
 
Some organic compounds melt through [[mesophase]]s, states of partial order between solid and liquid.
 
==Thermodynamics of melting==
{{main|Melting point}}
 
When a substance melts and the solid and liquid phases are in an equilibrium, it maintains a constant temperature, the melting point. The energy used for melting is a [[latent heat]]. This characterizes the process of melting as a first-order phase transition.
 
From a thermodynamics point of view, at the melting point the change in [[Gibbs free energy]] (<math>\Delta G</math>) of the material is zero, but the [[enthalpy]] (<math>H</math>) and the [[entropy]] (<math>S</math>) of the material are increasing (<math>\Delta H, \Delta S > 0</math>). Melting occurs when the Gibbs free energy of the liquid becomes lower than the solid for that material. The temperature at which this occurs is dependent on the ambient pressure.
 
Low-temperature [[helium]] is the only known exception to the general rule.<ref>{{Citation |last=Atkins |first=Peter |last2=Jones |first2=Loretta |year=2008 |title=Chemical Principles: The Quest for Insight |edition=4th |publisher=W. H. Freeman and Company |isbn=0-7167-7355-4 |page=236}}</ref> [[Helium-3]] has a negative enthalpy of fusion at temperatures below 0.3 K. [[Helium-4]] also has a very slightly negative enthalpy of fusion below 0.8 K. This means that, at appropriate constant pressures, heat must be ''removed'' from these substances in order to melt them.<ref>{{Citation |last=Ott |first=J. Bevan |last2=Boerio-Goates |first2=Juliana |year=2000 |title=Chemical Thermodynamics: Advanced Applications |publisher=Academic Press |isbn=0-12-530985-6 |pages=92–93}}</ref>
 
==Melting criteria==
 
Among the theoretical criteria for melting, the Lindemann <ref>F.A. Lindemann, Z. Phys. 11 (1910) 609–615.</ref> and Born <ref>M. Born, J. Chem. Phys. 7 (1939) 591–601.</ref> criteria are those most frequently used as a basis to analyse the melting conditions . The Lindemann criterion states that melting occurs because of vibrational instability, e.g. [[crystal]]s melt when the average amplitude of thermal vibrations of atoms is relatively high compared with interatomic distances, e.g. <''δu<sup>2</sup>''>1/2 > ''δ<sub>L</sub>R<sub>s</sub>'', where ''δu'' is the atomic displacement, the Lindemann parameter ''δ<sub>L</sub>'' ≈ 0.20...0.25 and ''R<sub>s</sub>'' is a half of the inter-atomic distance. The Lindemann melting criterion is supported by experimental data both for [[crystal]]line materials and for [[glass-liquid transition]]s in amorphous materials. The Born criterion is based on rigidity catastrophe caused by the vanishing elastic shear modulus, e.g. when the crystal no longer has sufficient rigidity to mechanically withstand load.
 
==Supercooling==
{{main|Supercooling}}
 
Under a standard set of conditions, the melting point of a substance is a characteristic property. The melting point is often equal to the [[melting point|freezing point]]. However, under carefully created conditions, supercooling or superheating past the melting or freezing point can occur. [[properties of water|Water]] on a very clean glass surface will often supercool several degrees below the freezing point without freezing. Fine emulsions of pure water have been cooled to −38 degrees Celsius without nucleation to form [[ice]].{{Citation needed|date=April 2008}}. Nucleation occurs due to fluctuations in the properties of the material. If the material is kept still there is often nothing (such a physical vibration) to trigger this change, and supercooling (or superheating) may occur. Thermodynamically, the supercooled liquid is in the metastable state with respect to the crystalline phase, and it is likely to crystallize suddenly.
 
==Melting of amorphous solids (glasses)==
 
Glasses are amorphous solids (e.g. amorphous materials that are at temperatures below the glass transition temperature) which are usually fabricated when the viscous molten material cools very rapidly to below its glass transition temperature, without sufficient time for a regular crystal lattice to form. Whether a material is liquid or solid depends primarily on the connectivity between its elementary building blocks so that solids are characterised by a high degree of connectivity where as fluids occur at lower connectivity of the structural blocks. Melting of a solid material can also be considered as a percolation via broken connections between particles e.g. connecting bonds.<ref>S.Y. Park and D. Stroud, Phys. Rev. B 67, 212202 (2003).</ref> In this approach melting of an amorphous material occurs when the broken bonds form a percolation cluster with ''T<sub>g</sub>'' dependent on quasi-equilibrium thermodynamic parameters of bonds e.g. on enthalpy (''H<sub>d</sub>'') and entropy (''S<sub>d</sub>'') of formation of bonds in a given system at given conditions:<ref>M.I. Ojovan, W.E. Lee. J. Non-Cryst. Solids, 356, 2534–2540 (2010).</ref>  
 
:<math>T_g = \frac{H_d}{S_d+ R \ln(\frac{1-f_c}{f_c})},</math>
 
where ''f<sub>c</sub>'' is the percolation threshold and ''R'' is the universal gas constant. Although ''H<sub>d</sub>'' and ''S<sub>d</sub>'' are not true equilibrium thermodynamic parameters and can depend on the cooling rate of a melt they can be found from available experimental data on [[viscosity of amorphous materials]].
 
==Premelting (surface melting)==
{{main|Premelting}}
 
Premelting (also: Surface melting) describes the fact that, even below its melting point <math>T_s</math>, quasi-liquid films can be observed on crystalline surfaces. The thickness of the film is temperature dependent. This effect is common for all crystalline materials. Premelting shows its effects in e.g. frost heave, the growth of snowflakes and, taking grain boundary interfaces into account, maybe even in the movement of glaciers.
 
==Related concepts==
{{Wiktionary|melting}}
 
In [[genetics]], melting [[DNA]] means to separate the double-stranded DNA into two single strands by heating or the use of chemical agents, cf. [[Polymerase chain reaction]].
 
==See also==
* [[List of elements]] providing melting points
* [[Phase diagram]]
* [[Zone melting]]
 
==References==
{{reflist}}
 
==References and further reading==
* [[Hagen Kleinert|Kleinert, Hagen]]. ''Gauge Fields in Condensed Matter'', Vol. II,  "[[Stress (physics)|STRESSES]] AND [[Crystallographic defect|DEFECTS]]; [[differential geometry|Differential Geometry]], Crystal Melting", pp.&nbsp;743–1456,  World Scientific (Singapore, 1989);  Paperback ISBN 9971-5-0210-0 '' (readable online [http://www.physik.fu-berlin.de/~kleinert/kleiner_reb1/contents2.html here])''
* C.Michael Hogan. 2011. [http://www.eoearth.org/article/Sulfur?topic=49557 ''sulfur''. Encyclopedia of Earth, eds. A.Jorgensen and C.J.Cleveland, National Council for Science and the environment, Washington DC]
 
{{Table of Phase Transitions}}
 
[[Category:Phase transitions]]
[[Category:Materials science]]

Latest revision as of 23:46, 8 January 2015

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Will there ever be a Sugarcoat Puppy love halt on Provoke Ardour HD?
As of this report, unmatched of the about pop apps or games on the cyberspace looks similar it's non-existent for that pad twist. Meanwhile, it is constantly on the order on the inclination of big top apps at deuce other salient app sellers online. Will the Martin Luther King Jr. troupe resolve to press release the pop candy-suppression bet on for KFHD owners, or will they stay put with the pasture of devices the feature bum be acquired on now?

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A portion of 'Confect Crush' players get so addicted to any extra secretion of dopamine by their brains, which they become addicted to the spirited itself and performing. The merchandising and play export at Shackle University, Prof Sudhir Kale, told tidings.com.au the mix of 'variable' and 'fixed' rewards victimized in the one-armed bandit political machine stake gambling diligence are progressively beingness replicated in wandering games, wish 'Candy Crush', concentrating on the Sami 'appetizing' personal effects.

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