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{{hatnote|This article outlines the historical development of the laws describing ideal gases.  For a detailed description of the ideal '''gas laws''' and their further development, see [[Ideal gas]], [[Ideal gas law]] and [[Gas]].}}
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The early gas laws were developed at the end of the 18th century, when scientists began to realize that relationships between the pressure, volume and temperature of a sample of gas could be obtained which would hold for all gases.  Gases behave in a similar way over a wide variety of conditions because to a good approximation they all have molecules which are widely spaced, and nowadays the equation of state for an ideal gas is derived from [[kinetic theory]]. The earlier gas laws are now considered as special cases of the ideal gas equation, with one or more of the variables held constant.
 
==Boyle's law==
{{Main|Boyle's law}}
 
Boyle's law shows that, at constant temperature, the product of an [[ideal gas|ideal gas's]] pressure and volume is always constant. It was published in 1662. It can be determined experimentally using a pressure gauge and a variable volume container. It can also be found through the use of logic; if a container, with a fixed number of molecules inside, is reduced in volume, more molecules will hit the sides of the container per unit time, causing a greater pressure.
 
As a mathematical equation, Boyle's law is:
 
:<math>P_1 V_1=P_2 V_2\,</math>
 
where ''P'' is the pressure (Pa), ''V'' the volume (m<sup>3</sup>) of a gas, and ''k''<sub>1</sub> (measured in [[joule]]s) is the constant from this equation—it is not the same as the constants from the other equations below.
 
This is known as Boyle's law which states: the volume of a given mass of gas is inversely proportional to its pressure, if the temperature remains constant. Mathematically this is:
 
<math> V = k/P </math>
 
where k is a constant (NOT Boltzmann's constant or Coulomb’s constant).
 
==Charles' law==
{{Main|Charles's law}}
 
Charles's Law, or the law of volumes, was found in 1787 by Jacques Charles. It says that, for an ideal gas at constant pressure, the volume is directly proportional to its [[temperature]].  
 
:<math> \frac{V_1}{T_1}=\frac{V_2}{T_2} \,</math>
 
==Gay-Lussac's law==
{{Main|Gay-Lussac's law}}
Gay-Lussac's law, or the pressure law, was found by [[Joseph Louis Gay-Lussac]] in 1809. It states that the pressure exerted on the sides of a container by an ideal gas of fixed volume is proportional to its temperature.
:<math> \frac{P_1}{T_1}=\frac{P_2}{T_2}</math>
 
==Avogadro's law==
{{Main|Avogadro's law}}
 
Avogadro's law states that the volume occupied by an ideal gas is proportional to the number of [[mole (unit)|moles]] present in the container. This gives rise to the [[molar volume]] of a gas, which at [[Standard conditions for temperature and pressure|STP]] is 22.4 dm<sup>3</sup> (or [[litres]]). The relation is given by
 
:<math>\frac{V_1}{n_1}=\frac{V_2}{n_2}    \,</math>
 
where n is equal to the number of moles of gas (the number of molecules divided by [[Avogadro's Number]]).
 
==Combined and ideal gas laws==
{{main|Ideal gas law}}
The [[combined gas law]] or general gas equation is formed by the combination of the three laws, and shows the relationship between the pressure, volume, and temperature for a fixed mass of gas:
 
:<math>PV = k_5T \,</math>
 
This can also be written as:
 
:<math> \qquad \frac {p_1V_1}{T_1}= \frac {p_2V_2}{T_2} </math>
 
With the addition of [[Avogadro's law]], the [[combined gas law]] develops into the [[ideal gas law]]:
 
:<math>PV = nRT \,</math>
 
where
 
:''P'' is pressure
:''V'' is volume
:''n'' is the number of moles
:''R'' is the universal gas constant
:''T'' is temperature (K)
 
where the constant, now named R, is the [[gas constant]] with a value of .08206 (atm∙L)/(mol∙K). An equivalent formulation of this law is:
 
:<math>PV = kNT \,</math>
 
where
 
:''P'' is the absolute pressure
:''V'' is the volume
:''N'' is the number of gas molecules
:''k'' is the Boltzmann constant (1.381×10<sup>−23 </sup>J·K<sup>−1</sup> in SI units)
:''T'' is the temperature (K)
 
These equations are exact only for an [[ideal gas]], which neglects various intermolecular effects (see [[real gas]]).  However, the ideal gas law is a good approximation for most gases under moderate pressure and temperature.
 
This law has the following important consequences:
# If temperature and pressure are kept constant, then the volume of the gas is directly proportional to the number of molecules of gas.
# If the temperature and volume remain constant, then the pressure of the gas changes is directly proportional to the number of molecules of gas present.
# If the number of gas molecules and the temperature remain constant, then the pressure is inversely proportional to the volume.
# If the temperature changes and the number of gas molecules are kept constant, then either pressure or volume (or both) will change in direct proportion to the temperature.
 
==Other gas laws==
* [[Graham's law]] states that the rate at which gas molecules [[diffusion|diffuse]] is inversely proportional to the square root of its density. Combined with Avogadro's law (i.e. since equal volumes have equal number of molecules) this is the same as being inversely proportional to the root of the molecular weight.
 
* [[Dalton's law]] of [[partial pressures]] states that the pressure of a mixture of gases simply is the sum of the [[partial pressures]] of the individual components. Dalton's Law is as follows:
 
:<math> P_{total} = P_1 + P_2 + P_3 + ... + P_n \equiv \sum_{i=1}^n P_i \,</math>,
 
'''OR'''
 
:<math> P_\mathrm{total} = P_\mathrm{gas} + P_\mathrm{H_2 O} \,</math>
 
where ''P''<sub>Total</sub> is the total pressure of the atmosphere,
''P''<sub>Gas</sub> is the pressure of the gas mixture in the atmosphere,
and ''P''<sub>H<sub>2</sub>O</sub> is the water pressure at that temperature.
 
* [[Henry's law]] states that:
:''At constant temperature, the amount of a given gas dissolved in a given type and volume of liquid is directly proportional to the [[partial pressure]] of that gas in equilibrium with that liquid.''
 
:<math> p = k_{\rm H}\, c</math>
 
==See also==
* [[Ideal gas law]]
 
==References==
* {{Cite book | author=Castka, Joseph F.; Metcalfe, H. Clark; Davis, Raymond E.; Williams, John E. | title=Modern Chemistry | publisher=Holt, Rinehart and Winston | year=2002 | isbn=0-03-056537-5}}
* {{Cite book | author=Guch, Ian | title=The Complete Idiot's Guide to Chemistry | publisher=Alpha, Penguin Group Inc. | year=2003 | isbn=1-59257-101-8}}
* {{Cite book | author=Zumdahl, Steven S | title=Chemical Principles | publisher=Houghton Mifflin Company | year=1998 | isbn=0-395-83995-5}}
 
{{DEFAULTSORT:Gas Laws}}
[[Category:Gas laws|*]]
[[Category:History of thermodynamics]]

Latest revision as of 17:34, 1 January 2015

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