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This page provides supplementary chemical data on [[ethylene]].
 
== Structure and properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Structure and properties
|-
| [[Index of refraction]]
| ? <!-- Please omit if not applicable -->
|-
| [[Dielectric constant]]
| ? ε<sub>0</sub> at ? °C <!-- Please omit if not applicable -->
|-
| [[Bond strength (chemistry)|Bond strength]]
| ? <!-- Specify which bond. Please omit if not applicable -->
|-
| [[Bond length]]
| C-C 133pm  C-H 108 pm
|-
| [[Bond angle]]
| 121.7 <!-- Specify which angle, e.g. Cl-P-O. Please omit if not applicable -->
|-
| [[Magnetic susceptibility]]
| ? <!-- Please omit if not applicable -->
|-
|}
 
== Thermodynamic properties == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | Phase behavior
|-
| [[Triple point]]
| 104 K (&minus;169 °C), 120 Pa
|-
| [[Critical point (thermodynamics)|Critical point]]
| 282.5 K (9.4 °C), 50.6 bar
|-
| [[Standard enthalpy change of fusion|Std enthalpy change<br/>of fusion]], Δ<sub>fus</sub>''H''<sup><s>o</s></sup>
| +3.35 kJ/mol
|-
| [[Standard entropy change of fusion|Std entropy change<br/>of fusion]], Δ<sub>fus</sub>''S''<sup><s>o</s></sup>
| +32.2 J/(mol·K)
|-
| [[Standard enthalpy change of vaporization|Std enthalpy change<br/>of vaporization]], Δ<sub>vap</sub>''H''<sup><s>o</s></sup>
| +13.5 kJ/mol
|-
| [[Standard entropy change of vaporization|Std entropy change<br/>of vaporization]], Δ<sub>vap</sub>''S''<sup><s>o</s></sup>
| ? J/(mol·K)
|-
! {{chembox header}} | Solid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>solid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>solid</sub>
| ? J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| ? J/(mol K)
|-
! {{chembox header}} | Liquid properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>liquid</sub>
| ? kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>liquid</sub>
| 117.8 J/(mol K)
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 67.4 J/(mol K)
|-
! {{chembox header}} | Gas properties
|-
| [[Standard enthalpy change of formation|Std enthalpy change<br/>of formation]], Δ<sub>f</sub>''H''<sup><s>o</s></sup><sub>gas</sub>
| +52.47 kJ/mol
|-
| [[Standard molar entropy]],<br/>''S''<sup><s>o</s></sup><sub>gas</sub>
| 219.32 J/(mol K)
|-
| [[Enthalpy of combustion]], Δ<sub>c</sub>''H''<sup><s>o</s></sup>
| –1387.4 kJ/mol
|-
| [[Heat capacity]], ''c<sub>p</sub>''
| 42.9 J/(mol K)
|-
| [[van der Waals equation|van der Waals' constants]]<ref name="lange1522">''Lange's Handbook of Chemistry'' 10th ed, pp 1522-1524</ref>
| a = 453.02 L<sup>2</sup> kPa/mol<sup>2</sup><br> b = 0.05714 liter per mole
|-
|}
 
==Vapor pressure of liquid==
{| border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: white; border-collapse: collapse; border-color: #C0C090;"
|-
| {{chembox header}} | '''P in mm of hg''' || 1 || 10 || 40 || 100 || 400 || 760 || 1520 || 3800 || 7600 || 15200 || 30400 ||
|-
| {{chembox header}} | '''T in °C''' || –168.3 || –153.2 || –141.3 || –131.8 || –113.9 || –103.7 || –90.8 || –71.1 || –52.8 || –29.1 || –1.5 || &nbsp;—
|}<br>
Table data obtained from ''CRC Handbook of Chemistry and Physics'', 44th ed.
 
[[Image:LogEthyleneVaporPressure.png|thumb|475px|left|'''log<sub>10</sub> of ethylene vapor pressure.''' Uses formula: <math>\scriptstyle \log_{10} P_{mmHg} = 6.74756 - \frac {585.00} {255.00+T}</math>, obtained from ''Lange's Handbook of Chemistry'', 10th ed.]]{{Clear}}
 
== Spectral data == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
{| border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"
! {{chembox header}} | [[UV/VIS spectroscopy|UV-Vis]]
|-
| [[Lambda-max|λ<sub>max</sub>]]
| ? [[Nanometre|nm]]
|-
| [[molar absorptivity|Extinction coefficient]], ε
| ?
|-
! {{chembox header}} | [[Infrared|IR]]
|-
| Major absorption bands
| 974&nbsp;cm<sup>&minus;1</sup>
|-
! {{chembox header}} | [[NMR Spectroscopy|NMR]]
|-
| [[Proton NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| [[Carbon-13 NMR]] <!-- Link to image of spectrum -->
| &nbsp;
|-
| Other NMR data <!-- Insert special data e.g. <sup>19</sup>F chem. shifts, omit if not used -->
| &nbsp;
|-
! {{chembox header}} | [[Mass Spectrometry|MS]]
|-
| Masses of <br>main fragments
| &nbsp; <!-- Give list of major fragments -->
|-
|}
 
== Material Safety Data Sheet == <!-- KEEP this header, it is linked to from the infobox on the main article page -->
 
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ([[Material safety data sheet|MSDS]]) for this chemical from a reliable source  such as [http://www.siri.org/msds/index.php SIRI], and follow its directions.
 
==References==
<references/>
*[http://webbook.nist.gov/chemistry/ NIST Standard Reference Database]
 
Except where noted otherwise, data relate to [[standard ambient temperature and pressure]].
 
[[wikipedia:Chemical infobox|Disclaimer]] applies.
 
{{DEFAULTSORT:Ethylene (Data Page)}}
[[Category:Chemical data pages]]

Revision as of 22:41, 6 January 2014

This page provides supplementary chemical data on ethylene.

Structure and properties

Structure and properties
Index of refraction ?
Dielectric constant ? ε0 at ? °C
Bond strength ?
Bond length C-C 133pm C-H 108 pm
Bond angle 121.7
Magnetic susceptibility ?

Thermodynamic properties

Phase behavior
Triple point 104 K (−169 °C), 120 Pa
Critical point 282.5 K (9.4 °C), 50.6 bar
Std enthalpy change
of fusion
, ΔfusHo
+3.35 kJ/mol
Std entropy change
of fusion
, ΔfusSo
+32.2 J/(mol·K)
Std enthalpy change
of vaporization
, ΔvapHo
+13.5 kJ/mol
Std entropy change
of vaporization
, ΔvapSo
? J/(mol·K)
Solid properties
Std enthalpy change
of formation
, ΔfHosolid
? kJ/mol
Standard molar entropy,
Sosolid
? J/(mol K)
Heat capacity, cp ? J/(mol K)
Liquid properties
Std enthalpy change
of formation
, ΔfHoliquid
? kJ/mol
Standard molar entropy,
Soliquid
117.8 J/(mol K)
Heat capacity, cp 67.4 J/(mol K)
Gas properties
Std enthalpy change
of formation
, ΔfHogas
+52.47 kJ/mol
Standard molar entropy,
Sogas
219.32 J/(mol K)
Enthalpy of combustion, ΔcHo –1387.4 kJ/mol
Heat capacity, cp 42.9 J/(mol K)
van der Waals' constants[1] a = 453.02 L2 kPa/mol2
b = 0.05714 liter per mole

Vapor pressure of liquid

P in mm of hg 1 10 40 100 400 760 1520 3800 7600 15200 30400
T in °C –168.3 –153.2 –141.3 –131.8 –113.9 –103.7 –90.8 –71.1 –52.8 –29.1 –1.5  —


Table data obtained from CRC Handbook of Chemistry and Physics, 44th ed.

log10 of ethylene vapor pressure. Uses formula: , obtained from Lange's Handbook of Chemistry, 10th ed.

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Spectral data

UV-Vis
λmax ? nm
Extinction coefficient, ε ?
IR
Major absorption bands 974 cm−1
NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
MS
Masses of
main fragments
 

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

References

  1. Lange's Handbook of Chemistry 10th ed, pp 1522-1524

Except where noted otherwise, data relate to standard ambient temperature and pressure.

Disclaimer applies.