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{{Multiple issues|cleanup =June 2008|technical=July 2012|refimprove =June 2008|
{{underlinked|date=October 2012}}
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In [[quantum mechanics]], a '''spin-exchange interaction''' preserves [[Total angular momentum quantum number|total angular momentum]] of the system but may allow other aspects of the system to change. When two spin-polarized [[atom]]s in their [[ground state]] experience a spin-exchange collision, the total [[Spin (physics)|spin]] of the atoms is preserved yet the orientation of the individual spins may change. For example, if atoms <math>A</math> and <math>B</math> are oppositely [[Spin polarization|polarized]], a spin-exchange collision reverses the spins:<ref>
{{cite journal
|author=Happer, W. and Tam, A. C.
|title=Effect of rapid spin exchange on the magnetic-resonance spectrum of alkali vapors
|journal=Physical Review A |year=1977 |volume=16|pages=1877–1891
|doi=10.1103/PhysRevA.16.1877
|url=http://link.aps.org/abstract/PRA/v16/p1877|issue=5
}}
</ref>
:<math>A(\uparrow) + B(\downarrow) \rightarrow A(\downarrow) + B(\uparrow)</math>
 
==In alkali metals==
In a typical vapor of [[alkali metal]] atoms, spin-exchange collisions are the dominant type of interaction between atoms. The collisions happen so rapidly that they only alter the state of the electron spins and do not significantly affect the nuclear spins. Thus, spin-exchange collisions between alkali metal atoms can change the [[hyperfine]] state of the atoms while preserving total [[angular momentum]] of the colliding pair. As a result, spin-exchange collisions cause [[quantum decoherence|decoherence]] in ensembles of polarized atoms precessing in the presence of a [[magnetic field]].
 
The time between spin-exchange collisions for a vapor of alkali metal atoms is
:<math>T_{se} = (\sigma_{se} n \bar{v})^{-1}</math>
where the spin exchange cross section for alkali metals such as K, Rb, and Cs is<ref>
{{cite journal
|author=HAPPER, WILLIAM
|title=Optical Pumping
|journal=Review of Modern Physics|year=1972 |volume=44|pages=169–249
|doi=10.1103/RevModPhys.44.169
|url=http://link.aps.org/abstract/RMP/v44/i2/p169_1|issue=2
|format=
}} {{dead link|date=July 2010}}
</ref>
:<math>\sigma_{se} = 2 \times 10^{-14} \ \mathrm{cm}^{2}</math>
and where <math>n</math> is the vapor density and <math>\bar{v}</math> is the average relative velocity given by the [[Maxwell-Boltzmann distribution]]:
:<math>\bar{v} = \sqrt{\frac{8 R T}{\pi m} }</math>
where <math>R</math> is the [[ideal gas constant]], <math>T</math> is the temperature, and <math>m</math> is the molar mass of the atoms.
 
== References ==
{{reflist}}
 
 
[[Category:Quantum mechanics]]

Revision as of 08:14, 4 February 2014

Template:Multiple issues

In quantum mechanics, a spin-exchange interaction preserves total angular momentum of the system but may allow other aspects of the system to change. When two spin-polarized atoms in their ground state experience a spin-exchange collision, the total spin of the atoms is preserved yet the orientation of the individual spins may change. For example, if atoms and are oppositely polarized, a spin-exchange collision reverses the spins:[1]

In alkali metals

In a typical vapor of alkali metal atoms, spin-exchange collisions are the dominant type of interaction between atoms. The collisions happen so rapidly that they only alter the state of the electron spins and do not significantly affect the nuclear spins. Thus, spin-exchange collisions between alkali metal atoms can change the hyperfine state of the atoms while preserving total angular momentum of the colliding pair. As a result, spin-exchange collisions cause decoherence in ensembles of polarized atoms precessing in the presence of a magnetic field.

The time between spin-exchange collisions for a vapor of alkali metal atoms is

where the spin exchange cross section for alkali metals such as K, Rb, and Cs is[2]

and where is the vapor density and is the average relative velocity given by the Maxwell-Boltzmann distribution:

where is the ideal gas constant, is the temperature, and is the molar mass of the atoms.

References

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