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{{Infobox ununennium}}
'''Ununennium''', also known as '''[[Mendeleev's predicted elements|eka]]-[[francium]]''' or element 119, is the temporary name of a [[chemical element]] in the [[periodic table]] that has the temporary symbol '''Uue''' and has the [[atomic number]] 119. To date, attempted syntheses of this element have been unsuccessful. Since it is below the [[alkali metals]] it might have properties similar to those of [[francium]] or [[caesium]] and thus be extremely reactive with water and air (though [[relativistic quantum chemistry|relativistic effects]] might make it less reactive than francium and caesium). A predicted oxidation state is +1; however, unlike all the other alkali metals, it is also predicted to show the +3 oxidation state.
 
Ununennium would be the first element in the eighth [[periodic table period|period]] of the [[periodic table]].
 
==Attempts at synthesis==
The synthesis of ununennium was attempted in 1985 by bombarding a target of [[einsteinium]]-254 with [[calcium]]-48 ions at the superHILAC accelerator at Berkeley, California:
:<math>\,^{254}_{99}\mathrm{Es} + \,^{48}_{20}\mathrm{Ca} \to \,^{302}_{119}\mathrm{Uue} ^{*} </math>
No atoms were identified, leading to a limiting yield of 300 [[barn (unit)|nb]].<ref>{{cite journal|title=Search for superheavy elements using <sup>48</sup>Ca + <sup>254</sup>Es<sup>g</sup> reaction|journal=Physical Reviews C|year=1985|pages=1760–1763|doi=10.1103/PhysRevC.32.1760|volume=32|issue=5|bibcode = 1985PhRvC..32.1760L|last1=Lougheed|first1=R.|last2=Landrum|first2=J.|last3=Hulet|first3=E.|last4=Wild|first4=J.|last5=Dougan|first5=R.|last6=Dougan|first6=A.|last7=Gäggeler|first7=H.|last8=Schädel|first8=M.|last9=Moody|first9=K. |displayauthors=11}}</ref>
 
As of May 2012, plans are under way to attempt to synthesize the isotopes <sup>295</sup>Uue and <sup>296</sup>Uue by bombarding a target of [[berkelium]] with [[titanium]] at the [[GSI Helmholtz Centre for Heavy Ion Research]] in [[Darmstadt]], Germany:<ref name="economist">[http://www.economist.com/node/21554502 Modern alchemy: Turning a line], [[The Economist]], May 12, 2012.</ref><ref>Düllmann, Christoph E. (October 20, 2011). [http://fias.uni-frankfurt.de/kollo/Duellmann_FIAS-Kolloquium.pdf Superheavy Element Research: News from GSI and Mainz]. Johannes Gutenberg University Mainz; GSI Helmholtzzentrum für Schwerionenforschung GmbH; Darmstadt Helmholtz Institute Mainz.</ref>
:<math>\,^{249}_{97}\mathrm{Bk} + \,^{50}_{22}\mathrm{Ti} \to \,^{296}_{119}\mathrm{Uue} \,+3\,^{1}_{0}\mathrm{n}</math>
 
:<math>\,^{249}_{97}\mathrm{Bk} + \,^{50}_{22}\mathrm{Ti} \to \,^{295}_{119}\mathrm{Uue} \,+4\,^{1}_{0}\mathrm{n}</math>
 
==Predicted decay characteristics==
The alpha-decay half-lives of 1700 nuclei with 100 ≤ Z ≤ 130 have been calculated in a quantum tunneling model with alpha-decay Q-values from different mass estimates.<ref name=npa07>{{cite journal|journal=Nucl. Phys. A|volume=789|pages=142–154|year=2007|title=Predictions of alpha decay half lives of heavy and superheavy elements|author=Chowdhury, P. Roy; Samanta, C. and Basu, D. N. |doi=10.1016/j.nuclphysa.2007.04.001|bibcode=2007NuPhA.789..142S|arxiv = nucl-th/0703086 }}</ref><ref>{{cite journal|journal=Phys. Rev. C|volume=77|pages=044603|year=2008|title=Search for long lived heaviest nuclei beyond the valley of stability|author=Chowdhury, P. Roy; Samanta, C. and Basu, D. N. |doi=10.1103/PhysRevC.77.044603|issue=4|bibcode=2008PhRvC..77d4603C|arxiv = 0802.3837 }}</ref><ref>{{cite journal|journal=At. Data & Nucl. Data Tables|volume=94|pages=781–806|year=2008|title=Nuclear half-lives for α -radioactivity of elements with 100 ≤ Z ≤ 130|author=Chowdhury, P. Roy; Samanta, C. and Basu, D. N. |doi=10.1016/j.adt.2008.01.003|issue=6|bibcode=2008ADNDT..94..781C|arxiv = 0802.4161 }}</ref> The alpha-decay half-lives predicted for <sup>291–307</sup>119 are of the order of micro-seconds. The highest value of the alpha-decay half-life predicted in the quantum tunneling model with the mass estimates from a macroscopic-microscopic model is ~485 microseconds for the isotope <sup>294</sup>119. For <sup>302</sup>119 it is ~163 microseconds.
 
==Target-projectile combinations leading to Z=119 compound nuclei==
The below table contains various combinations of targets and projectiles which could be used to form compound nuclei with an atomic number of 119.
 
{|class="wikitable" style="text-align:center"
 
!Target!!Projectile!!CN!!Attempt result
|-
!<sup>254</sup>Es
|<sup>48</sup>Ca||<sup>302</sup>Uue||{{no|Failure to date}}
|-
!<sup>249</sup>Bk
|<sup>50</sup>Ti||<sup>299</sup>Uue||{{unk|Planned reaction}}
|}<!--Please use {{yes|Successful reaction}} for successes, thanks-->
 
==Theoretical calculations on evaporation cross sections==
The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.
 
DNS = Di-nuclear system; σ = cross section
 
{|class="wikitable" style="text-align:center"
|-
!Target!!Projectile!!CN!!Channel (product)!!σ <sub>max</sub>!!Model!!Ref
|-
!<sup>254</sup>Es
|<sup>48</sup>Ca||<sup>302</sup>Uue||3n (<sup>299</sup>Uue)||0.5 pb||DNS||<ref>{{cite journal|arxiv=0803.1117|doi=10.1016/j.nuclphysa.2008.11.003|title=Production of heavy and superheavy nuclei in massive fusion reactions|year=2009|author=Feng, Z|journal=Nuclear Physics A|volume=816|page=33|last2=Jin|first2=G|last3=Li|first3=J|last4=Scheid|first4=W|bibcode=2009NuPhA.816...33F}}</ref>
|}
 
==Extrapolated chemical properties==
Ununennium is expected to behave normally for an alkali metal and exhibit a strong +1 [[oxidation state]]. However, the energetic properties of its [[valence electron]] would increase its first [[ionization energy]], making it less reactive than expected and more like [[potassium]] than [[caesium]] chemically. This would also decrease the [[metallic radius|metallic]] and [[ionic radius|ionic radii]] of ununennium.<ref name=EB>{{cite web|author=Seaborg|url=http://www.britannica.com/EBchecked/topic/603220/transuranium-element|title=transuranium element (chemical element)|publisher=Encyclop&aelig;dia Britannica|date=c. 2006|accessdate=2010-03-16}}</ref> Ununennium is also predicted to be the first alkali metal to display the +3 oxidation state, due to the ionization energy of the 7p<sub>3/2</sub> electrons, which is predicted to be very low.<ref name=Haire/>
 
==See also==
*[[Extended periodic table]]
 
==References==
{{clear}}
{{Reflist|colwidth=30em}}
 
{{Compact extended periodic table}}
 
[[Category:Chemical elements]]
[[Category:Alkali metals]]
[[Category:Hypothetical chemical elements]]

Revision as of 19:14, 28 January 2014

Template:Infobox ununennium Ununennium, also known as eka-francium or element 119, is the temporary name of a chemical element in the periodic table that has the temporary symbol Uue and has the atomic number 119. To date, attempted syntheses of this element have been unsuccessful. Since it is below the alkali metals it might have properties similar to those of francium or caesium and thus be extremely reactive with water and air (though relativistic effects might make it less reactive than francium and caesium). A predicted oxidation state is +1; however, unlike all the other alkali metals, it is also predicted to show the +3 oxidation state.

Ununennium would be the first element in the eighth period of the periodic table.

Attempts at synthesis

The synthesis of ununennium was attempted in 1985 by bombarding a target of einsteinium-254 with calcium-48 ions at the superHILAC accelerator at Berkeley, California:

No atoms were identified, leading to a limiting yield of 300 nb.[1]

As of May 2012, plans are under way to attempt to synthesize the isotopes 295Uue and 296Uue by bombarding a target of berkelium with titanium at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt, Germany:[2][3]

Predicted decay characteristics

The alpha-decay half-lives of 1700 nuclei with 100 ≤ Z ≤ 130 have been calculated in a quantum tunneling model with alpha-decay Q-values from different mass estimates.[4][5][6] The alpha-decay half-lives predicted for 291–307119 are of the order of micro-seconds. The highest value of the alpha-decay half-life predicted in the quantum tunneling model with the mass estimates from a macroscopic-microscopic model is ~485 microseconds for the isotope 294119. For 302119 it is ~163 microseconds.

Target-projectile combinations leading to Z=119 compound nuclei

The below table contains various combinations of targets and projectiles which could be used to form compound nuclei with an atomic number of 119.

Target Projectile CN Attempt result
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Underneath this arrangement, it's a healthy transaction and competition between purchaser and vendor's brokers. Of course buyer's agent will work very laborious to get you the listings to view and negotiate for you the property you need to purchase, while the vendor's agent would do the identical for their seller to earn the commission. Right now, we have lost all confidence in obtaining our dream house and at a superb deal by means of agents here except we wish to undergo this very frustrating and worrying dwelling buying course of in Singapore again. WE would in all probability just purchase in Hong Kong or again home in New York where real property agents have been more professionally educated and operated. bookstores and shops Mighty Minds Singapore Streets Listing Expat Properties
249Bk 50Ti 299Uue Template:Unk

Theoretical calculations on evaporation cross sections

The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

DNS = Di-nuclear system; σ = cross section

Target Projectile CN Channel (product) σ max Model Ref
254Es 48Ca 302Uue 3n (299Uue) 0.5 pb DNS [7]

Extrapolated chemical properties

Ununennium is expected to behave normally for an alkali metal and exhibit a strong +1 oxidation state. However, the energetic properties of its valence electron would increase its first ionization energy, making it less reactive than expected and more like potassium than caesium chemically. This would also decrease the metallic and ionic radii of ununennium.[8] Ununennium is also predicted to be the first alkali metal to display the +3 oxidation state, due to the ionization energy of the 7p3/2 electrons, which is predicted to be very low.[9]

See also

References

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Template:Compact extended periodic table

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  2. Modern alchemy: Turning a line, The Economist, May 12, 2012.
  3. Düllmann, Christoph E. (October 20, 2011). Superheavy Element Research: News from GSI and Mainz. Johannes Gutenberg University Mainz; GSI Helmholtzzentrum für Schwerionenforschung GmbH; Darmstadt Helmholtz Institute Mainz.
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    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

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    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  6. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  7. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
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