Alkyne

A 3D model of ethyne (acetylene), the simplest alkyne

In organic chemistry, an alkyne is an unsaturated hydrocarbon which has at least one carbon—carbon triple bond between two carbon atoms. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula To make the tax system more progressive, the Authorities is elevating property tax rates for top-end residential properties in singapore hdb rental Finances 2013, with the largest will increase making use of to funding properties that aren't occupied by their house owners.

The inventory market and property market are extremely correlated. Take a look at our chartbooks for the latest stock market costs and economic indicators. Associated charts are introduced facet by side to facilitate comparability and analysis Rates of interest are extraordinarily low, globally and in Singapore, and continue so as to add gas to our property market. We now have to take this additional spherical of measures now, to test latest market traits and keep away from a extra serious correction in costs additional down the highway,ђ mentioned Deputy Prime Minister and Minister for Finance Tharman Shanmugaratnam. This may imply a rise in property taxes paid for non-proprietor-occupied houses with annual values of above $30,000. These properties belong to the highest one-third of all non-proprietor-occupied homes.

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SSD at 12 per cent (increased than up to 2 per cent currently), if the property is bought within the second yr of purchase, i.e. the property is held for greater than 1 12 months and as much as 2 years. SSD at 8 per cent (larger than as much as 1 per cent presently), if the property is sold in the third yr of purchase, i.e. the property is held for greater than 2 years and up to three years. SSD at four per cent (no SSD currently), if the property is bought within the fourth 12 months of buy, i.e. the property is held for greater than three years and as much as four years. The Government will proceed to monitor the property market intently and take additional steps to advertise a stable and sustainable property market if crucial. b) borrow up to 30% of property worth when you've got an present housing loan

For the prevailing 10% tax price to apply, the property must have acquired planning approval for the above use. No application to IRAS is required. Owner-Occupier Tax Charges Annual Worth($) Efficient 1 Jan 2014 Efficient 1 Jan 2015 First 8,000 On eleven Jan 2013, the Government announced the revised ABSD charges applicable to purchases or acquisitions of residential properties on or after 12 Jan 2013. The place an Choice To Purchase has been granted on and earlier than eleven Jan 2013 and exercised thereafter on or before 1 Feb 2013 without any extension of the option validity interval, the outdated ABSD rates might apply subject to approval for remission by IRAS (see Remission/ Refund ). Posted by Edison Foo December 13, 2013 Open for booking NOW !!! Posted by Edison Foo October 22, 2013

Rising workplace sector leads actual property market performance, whereas prime retail and enterprise park segments moderate and residential sector continues in decline Latest knowledge from Actual Capital Analytics (RCA) exhibits real estate advisory agency suggested on the most deals by value in the area in 2013 An alternative choice to estate duties is an inheritance tax, which assesses beneficiaries relatively than the estate of the deceased, and will be simpler to administer and accumulate, particularly when property are held abroad. There is no such thing as a cause for a corporation or particular person not to buy. Do not ask me why they pay hire. A few of them pay even lease to overseas owners or overseas owned firms. District 18, 999 yr LH residence Residential units & 57 business models Posted by Edison Foo July three, 2013

This prediction of how the markets shall be influenced by Boomers assumes that the overall actual estate market will proceed to improve and be boosted by a scarcity of supply for various years. Boomers in lots of areas are sitting on actual property price a fortune, but they don't have a number of cash; the "golden handcuffs" of actual property riches they cannot afford to promote. If they sit on their houses, inventories out there for consumers will likely be lowered and home prices will enhance with this shortage of provide._n57 year old Roof Plumber Avery Kamm from Lloydminster, has many passions which include frisbee golf (frolf), property developers in singapore and snorkeling. Last year just completed buy a house in singapore trip Konso Cultural Landscape._2n-2. Alkynes are traditionally known as acetylenes, although the name acetylene also refers specifically to C₂H₂, known formally as ethyne using IUPAC nomenclature. Like other hydrocarbons, alkynes are generally hydrophobic but tend to be more reactive.

Chemical properties

Alkynes are characteristically more unsaturated than alkenes. Thus they add two equivalents of bromine whereas an alkene adds only one equivalent. Other reactions are listed below. In some reactions, alkynes are less reactive than alkenes. For example, in a molecule with an -ene and an -yne group, addition occurs preferentially at the -ene. Possible explanations involve the two π-bonds in the alkyne delocalising, which would reduce the energy of the π-systemPotter or Ceramic Artist Truman Bedell from Rexton, has interests which include ceramics, best property developers in singapore developers in singapore and scrabble. Was especially enthused after visiting Alejandro de Humboldt National Park. or the stability of the intermediates during the reaction. They show greater tendency to polymerize or oligomerize than alkenes do. The resulting polymers, called polyacetylenes (which do not contain alkyne units) are conjugated and can exhibit semiconducting properties.

Structure and bonding

In acetylene, the H–C≡C bond angles are 180°. By virtue of this bond angle, alkynes tend to be rod-like. Correspondingly, cyclic alkynes are rare. Benzyne is highly unstable. The C≡C bond distance of 121 picometers is much shorter than the C=C distance in alkenes (134 pm) or the C-C bond in alkanes (153 pm).

Illustrative alkynes: a, acetylene, b, two depictions of propyne, c, 1-butyne, d, 2-butyne, e, the naturally-occurring 1-phenylhepta-1,3,5-triyne, and f, the strained cycloheptyne. Triple bonds are highlighted blue.

The triple bond is very strong with a bond strength of 839 kJ/mol. The sigma bond contributes 369 kJ/mol, the first pi bond contributes 268 kJ/mol and the second pi-bond of 202 kJ/mol bond strength. Bonding usually discussed in the context of molecular orbital theory, which recognizes the triple bond as arising from overlap of s and p orbitals. In the language of valence bond theory, the carbon atoms in an alkyne bond are sp hybridized: they each have two unhybridized p orbitals and two sp hybrid orbitals. Overlap of an sp orbital from each atom forms one sp-sp sigma bond. Each p orbital on one atom overlaps one on the other atom, forming two pi bonds, giving a total of three bonds. The remaining sp orbital on each atom can form a sigma bond to another atom, for example to hydrogen atoms in the parent acetylene. The two sp orbitals project on opposite sides of the carbon atom.

Terminal and internal alkynes

Internal alkynes feature carbon substituents on each acetylenic carbon. Symmetrical examples include diphenylacetylene and 3-hexyne.

Terminal alkynes have the formula RC₂H. An example is methylacetylene (propyne using IUPAC nomenclature). Terminal alkynes, like acetylene itself, are mildly acidic, with pK_a values of around 25. They are far more acidic than alkenes and alkanes, which have pK_a values of around 40 and 50, respectively. The acidic hydrogen on terminal alkynes can be replaced by a variety of groups resulting in halo-, silyl-, and alkoxoalkynes. The carbanions generated by deprotonation of terminal alkynes are called acetylides.

Synthesis

Commercially, the dominant alkyne is acetylene itself, which is used as a fuel and a precursor to other compounds, e.g., acrylates. Hundreds of millions of kilograms are produced annually by partial oxidation of natural gas:

2 CH₄ + 3/2 O₂ → HC≡CH + 3 H₂O

Propyne, also industrially useful, is also prepared by thermal cracking of hydrocarbons. Most other industrially useful alkyne derivatives are prepared from acetylene, e.g. via condensation with formaldehyde.

Specialty alkynes are prepared by dehydrohalogenation of vicinal alkyl dihalides or vinyl halides. Metal acetylides can be coupled with primary alkyl halides. Via the Fritsch-Buttenberg-Wiechell rearrangement, alkynes are prepared from vinyl bromides. Alkynes can be prepared from aldehydes using the Corey-Fuchs reaction and from aldehydes or ketones by the Seyferth–Gilbert homologation. In the alkyne zipper reaction, alkynes are generated from other alkynes by treatment with a strong base.

Reactions

Featuring a reactive functional group, alkynes participate in many organic reactions.

Addition of hydrogen, halogens, and related reagents

Alkynes characteristically undergo reactions that show that they are "doubly unsaturated", meaning that each alkyne unit is capable of adding two equivalents of H₂, halogens or related HX reagents (X = halide, pseudohalide, etc.). Depending on catalysts and conditions, alkynes add one or two equivalents of hydrogen. Hydrogenation to the alkene is usually more desirable since alkanes are less useful:

RC≡CR' + H₂ → cis-RCH=CR'H

The largest scale application of this technology is the conversion of acetylene to ethylene in refineries. The steam cracking of alkanes affords a few percent acetylene, which is selectively hydrogenated in the presence of a palladium/silver catalyst. For more complex alkynes, the Lindlar catalyst is widely recommended to avoid formation of the alkane, for example in the conversion of phenylacetylene to styrene.

Application Lindlar Catalyst

Similarly, halogenation of alkynes gives the vinyl dihalides or alkyl tetrahalides:

RC≡CR' + 2 Br₂ → RCBr₂CRBr₂

The addition of nonpolar E-H bonds across C≡C is general for silanes, boranes, and related hydrides. The hydroboration of alkynes gives vinylic boranes which oxidize to the corresponding aldehyde or ketone. In the thiol-yne reaction the substrate is a thiol.

Hydrohalogenation gives the corresponding vinyl halides or alkyl dihalides, again depending on the number of equivalents of HX added. The addition of water to alkynes is a related reaction except the initial enol intermediate converts to the ketone or aldehyde. Illustrative is the hydration of phenylacetylene gives acetophenone, and the (Ph₃P)AuCH₃-catalyzed hydration of 1,8-nonadiyne to 2,8-nonanedione:

PhC≡CH + H₂O → PhCOCH₃

HC≡CC₆H₁₂C≡CH + 2H₂O → CH₃COC₆H₁₂COCH₃

Cycloadditions and oxidation

Alkynes undergo diverse cycloaddition reactions. Most notable is the Diels–Alder reaction with 1,3-dienes to give 1,4-cyclohexadienes. This general reaction has been extensively developed and electrophilic alkynes are especially effective dienophiles. The "cycloadduct" derived from the addition of alkynes to 2-pyrone eliminates carbon dioxide to give the aromatic compound. Other specialized cycloadditions include multicomponent reactions such as alkyne trimerisation to give aromatic compounds and the [2+2+1]cycloaddition of an alkyne, alkene and carbon monoxide in the Pauson–Khand reaction. Non-carbon reagents also undergo cyclization, e.g. Azide alkyne Huisgen cycloaddition to give triazoles. Cycloaddition processes involving alkynes are often catalyzed by metals, e.g. enyne metathesis and alkyne metathesis, which allows the scrambling of carbyne (RC) centers:

RC≡CR + R'C≡CR' ${\overrightarrow {\leftarrow }}$ 2 RC≡CR'

Oxidative cleavage of alkynes proceeds via cycloaddition to metal oxides. Most famously, potassium permanganate converts alkynes to a pair of carboxylic acids.

Reactions specific for terminal alkynes

In addition to undergoing the reactions characteristic of internal alkynes, terminal alkynes are reactive as weak acids, with pK_a values (25) between that of ammonia (35) and ethanol (16). The acetylide conjugate base is stabilized as a result of the high s character of the sp orbital, in which the electron pair resides. Electrons in an s orbital benefit from closer proximity to the positively charged atom nucleus, and are therefore lower in energy. Treatment of terminal alkynes with a strong base gives the corresponding metal acetylides:

RC≡CH + MX → RC≡CM + HX (MX = NaNH₂, LiBu, RMgX)

The reactions of alkynes with certain metal cations, e.g. Ag⁺ also gives acetylides. Thus, few drops of diamminesilver(I) hydroxide (Ag(NH₃)₂OH) reacts with terminal alkynes signaled by formation of a white precipitate of the silver acetylide. Acetylide derivatives are synthetically useful nucleophiles that participate in C-C bond forming reactions, as illustrated in the area called "Reppe Chemistry".

In the Favorskii reaction, terminal alkynes add to carbonyl compounds to give the hydroxyalkyne. Coupling of terminal alkynes to give di-alkynes is effected in the Cadiot-Chodkiewicz coupling, Glaser coupling, and the Eglinton coupling reactions. Terminal alkynes can also be coupled to aryl or vinyl halides as in the Sonogashira coupling.

Alkynes in nature and medicine

According to Ferdinand Bohlmann, the first naturally occurring acetylenic compound, dehydromatricaria ester, was isolated from an Artemisia species in 1826. In the nearly two centuries that have followed, well over a thousand naturally occurring acetylenes have been discovered and reported. Polyynes, a subset of this class of natural products, have been isolated from a wide variety of plant species, cultures of higher fungi, bacteria, marine sponges, and corals. Some acids like tariric acid contains an alkyne group. Diynes and triynes, species with the linkage RC≡C-C≡CR' and RC≡C-C≡C-C≡CR' respectively, occur in certain plants (Ichthyothere, Chrysanthemum, Cicuta, Oenanthe and other members of the Asteraceae and Apiaceae families). Some examples are cicutoxin, oenanthotoxin, falcarinol and carotatoxin. These compounds are highly bioactive, e.g. as nematocides. 1-Phenylhepta-1,3,5-triyne is illustrative of a naturally occurring triyne.

Alkynes occur in some pharmaceuticals, including the contraceptive norethynodrel. A carbon–carbon triple bond is also present in marketed drugs such as the antiretroviral Efavirenz and the antifungal Terbinafine. Molecules called ene-diynes feature a ring containing an alkene ("ene") between two alkyne groups ("diyne"). These compounds, e.g. calicheamicin, are some of the most aggressive antitumor drugs known, so much so that the ene-diyne subunit is sometimes referred to as a "warhead." Ene-diynes undergo rearrangement via the Bergman cyclization, generating highly reactive radical intermediates that attack DNA within the tumor.

See also

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• -yne
• cycloalkyne

References

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