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This page provides supplementary chemical data on nitromethane.
Material Safety Data Sheet
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS is available from Mallinckrodt Baker.
Structure and properties
Structure and properties | |
---|---|
Index of refraction, nD | 1.3935 at 20°C |
Abbe number | ? |
Dielectric constant, εr | 35.87 ε0 at 30 °C |
Bond strength | ? |
Bond length | ? |
Bond angle | ? |
Magnetic susceptibility | ? |
Surface tension[1] | 39.8 dyn/cm at 0°C 36.8 dyn/cm at 20°C 26.1 dyn/cm at 100°C |
Viscosity[2] | 0.853 mPa·s at 0°C 0.620 mPa·s at 25°C |
Thermodynamic properties
Phase behavior | |
---|---|
Triple point | 244.77 K (–23.38 °C), ? Pa |
Critical point | 588 K (315 °C), 5870 kPa |
Std enthalpy change of fusion, ΔfusH |
9.7 kJ/mol |
Std entropy change of fusion, ΔfusS |
39.6 J/(mol·K) |
Std enthalpy change of vaporization, ΔvapH |
38.3 kJ/mol |
Std entropy change of vaporization, ΔvapS |
128.36 J/(mol·K) |
Solid properties | |
Std enthalpy change of formation, ΔfH |
? kJ/mol |
Standard molar entropy, S |
? J/(mol K) |
Heat capacity, cp | ? J/(mol K) |
Liquid properties | |
Std enthalpy change of formation, ΔfH |
–113 kJ/mol |
Standard molar entropy, S |
171.75 J/(mol K) |
Enthalpy of combustion, ΔcH |
–709 kJ/mol |
Heat capacity, cp | 105.98 J/(mol K) |
Gas properties | |
Std enthalpy change of formation, ΔfH |
–81 kJ/mol |
Standard molar entropy, S |
? J/(mol K) |
Heat capacity, cp[3] | 57.3 J/(mol K) at 25°C |
Vapor pressure of liquid
P in mm Hg | 1 | 10 | 40 | 100 | 400 | 760 |
T in °C | –29.0 | 2.8 | 27.5 | 46.6 | 82.0 | 101.2 |
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.
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Distillation data
|
|
Spectral data
UV-Vis | |
---|---|
λmax | ? nm |
Extinction coefficient, ε | ? |
IR | |
Major absorption bands | ? cm−1 |
NMR | |
Proton NMR | |
Carbon-13 NMR | |
Other NMR data | |
MS | |
Masses of main fragments |
References
- ↑ Lange's Handbook of Chemistry, 10th ed. pp 1661-1663
- ↑ CRC Handbook of Chemistry and Physics, 44th ed. pp 2258-2263
- ↑ 3.0 3.1 Template:Cite web
- ↑ 4.0 4.1 Template:Cite web
Except where noted otherwise, data relate to standard ambient temperature and pressure.
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