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Isotope geochemistry is an aspect of geology based upon study of the natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal information about the ages and origins of rock, air or water bodies, or processes of mixing between them.

Stable isotope geochemistry is largely concerned with isotopic variations arising from mass-dependent isotope fractionation, whereas radiogenic isotope geochemistry is concerned with the products of natural radioactivity.

Stable isotope geochemistry

For most stable isotopes, the magnitude of fractionation from kinetic and equilibrium fractionation is very small; for this reason, enrichments are typically reported in "per mil" (‰, parts per thousand).[1] These enrichments (δ) represent the ratio of heavy isotope to light isotope in the sample over the ratio of a standard. That is,

Carbon

Carbon has two stable isotopes, 12C and 13C, and one radioactive isotope, 14C. Carbon isotope ratios are measured against Vienna Pee Dee Belemnite (VPDB).[2] They have been used to track ocean circulation, among other things.

Carbon stable isotopes are fractionated primarily by photosynthesis (Faure, 2004). The 13C/12C ratio is also an indicator of paleoclimate: a change in the ratio in the remains of plants indicates a change in the amount of photosynthetic activity, and thus in how favorable the environment was for the plants.

During photosynthesis, organisms using the C3 pathway show different enrichments compared to those using the C4 pathway, allowing scientists not only to distinguish organic matter from abiotic carbon, but also what type of photosynthetic pathway the organic matter was using.[1]

Nitrogen

Nitrogen has two stable isotopes, 14N, and 15N. The ratio between these is measured relative to nitrogen in ambient air.[2] Nitrogen ratios are frequently linked to agricultural activities. Nitrogen isotope data has also been used to measure the amount of exchange of air between the stratosphere and troposphere using data from the greenhouse gas N2O.[3]

Oxygen

Oxygen has three stable isotopes, 16O, 17O, and 18O. Oxygen ratios are measured relative to Vienna Standard Mean Ocean Water (VSMOW) or Vienna Pee Dee Belemnite (VPDB).[2] Variations in oxygen isotope ratios are used to track both water movement, paleoclimate,[1] and atmospheric gases such as ozone and carbon dioxide.[4] Typically, the VPDB oxygen reference is used for paleoclimate, while VSMOW is used for most other applications.[1] Oxygen isotopes appear in anomalous ratios in atmospheric ozone, resulting from mass-independent fractionation.[5] Isotope ratios in fossilized foraminifera have been used to deduce the temperature of ancient seas.[6]

Sulfur

Sulfur has four stable isotopes, with the following abundances: 32S (0.9502), 33S (0.0075), 34S (0.0421) and 36S (0.0002). These abundances are compared to those found in Cañon Diablo troilite.[4] Variations in sulfur isotope ratios are used to study the origin of sulfur in an orebody and the temperature of formation of sulfur–bearing minerals.[7]

Radiogenic isotope geochemistry

Radiogenic isotopes provide powerful tracers for studying the ages and origins of Earth systems.[8] They are particularly useful to understand mixing processes between different components, because (heavy) radiogenic isotope ratios are not usually fractionated by chemical processes.

Radiogenic isotope tracers are most powerful when used together with other tracers: The more tracers used, the more control on mixing processes. An example of this application is to the evolution of the Earth's crust and Earth's mantle through geological time.

Lead-lead isotope geochemistry

Lead has four stable isotopes - 204Pb, 206Pb, 207Pb, 208Pb and one common radioactive isotope 202Pb with a half-life of ~53,000 years.

Lead is created in the Earth via decay of transuranic elements, primarily uranium and thorium.

Lead isotope geochemistry is useful for providing isotopic dates on a variety of materials. Because the lead isotopes are created by decay of different transuranic elements, the ratios of the four lead isotopes to one another can be very useful in tracking the source of melts in igneous rocks, the source of sediments and even the origin of people via isotopic fingerprinting of their teeth, skin and bones.

It has been used to date ice cores from the Arctic shelf, and provides information on the source of atmospheric lead pollution.

Lead-lead isotopes has been successfully used in forensic science to fingerprint bullets, because each batch of ammunition has its own peculiar 204Pb/206Pb vs 207Pb/208Pb ratio.

Samarium-neodymium

Mining Engineer (Excluding Oil ) Truman from Alma, loves to spend time knotting, largest property developers in singapore developers in singapore and stamp collecting. Recently had a family visit to Urnes Stave Church. Samarium-neodymium is an isotope system which can be utilised to provide a date as well as isotopic fingerprints of geological materials, and various other materials including archaeological finds (pots, ceramics).

147Sm decays to produce 143Nd with a half life of 1.06x1011 years.

Dating is achieved usually by trying to produce an isochron of several minerals within a rock specimen. The initial 143Nd/144Nd ratio is determined.

This initial ratio is modelled relative to CHUR - the Chondritic Uniform Reservoir - which is an approximation of the chondritic material which formed the solar system. CHUR was determined by analysing chondrite and achondrite meteorites.

The difference in the ratio of the sample relative to CHUR can give information on a model age of extraction from the mantle (for which an assumed evolution has been calculated relative to CHUR) and to whether this was extracted from a granitic source (depleted in radiogenic Nd), the mantle, or an enriched source.

Rhenium-osmium

Rhenium and osmium are siderophile elements which are present at very low abundances in the crust. Rhenium undergoes radioactive decay to produce osmium. The ratio of non-radiogenic osmium to radiogenic osmium throughout time varies.

Rhenium prefers to enter sulfides more readily than osmium. Hence, during melting of the mantle, rhenium is stripped out, and prevents the osmium-osmium ratio from changing appreciably. This locks in an initial osmium ratio of the sample at the time of the melting event. Osmium-osmium initial ratios are used to determine the source characteristic and age of mantle melting events.

Noble gas isotopes

Natural isotopic variations amongst the noble gases result from both radiogenic and nucleogenic production processes. Because of their unique properties, it is useful to distinguish them from the conventional radiogenic isotope systems described above.

Helium-3

Helium-3 was trapped in the planet when it formed. Some 3He is being added by meteoric dust, primarily collecting on the bottom of oceans (although due to subduction, all oceanic tectonic plates are younger than continental plates). However, 3He will be degassed from oceanic sediment during subduction, so cosmogenic 3He is not affecting the concentration or noble gas ratios of the mantle.

Helium-3 is created by cosmic ray bombardment, and by lithium spallation reactions which generally occur in the crust. Lithium spallation is the process by which a high-energy neutron bombards a lithium atom, creating a 3He and a 4He ion. This requires significant lithium to adversely affect the 3He/4He ratio.

All degassed helium is lost to space eventually, due to the average speed of helium exceeding the escape velocity for the Earth. Thus, it is assumed the helium content and ratios of Earth's atmosphere have remained essentially stable.

It has been observed that 3He is present in volcano emissions and oceanic ridge samples. How 3He is stored in the planet is under investigation, but it is associated with the mantle and is used as a marker of material of deep origin.

Due to similarities in helium and carbon in magma chemistry, outgassing of helium requires the loss of volatile components (water, carbon dioxide) from the mantle, which happens at depths of less than 60 km. However, 3He is transported to the surface primarily trapped in the crystal lattice of minerals within fluid inclusions.

Helium-4 is created by radiogenic production (by decay of uranium/thorium-series elements). The continental crust has become enriched with those elements relative to the mantle and thus more He4 is produced in the crust than in the mantle.

The ratio (R) of 3He to 4He is often used to represent 3He content. R usually is given as a multiple of the present atmospheric ratio (Ra).

Common values for R/Ra:

  • Old continental crust: less than 1
  • mid-ocean ridge basalt (MORB): 7 to 9
  • Spreading ridge rocks: 9.1 plus or minus 3.6
  • Hotspot rocks: 5 to 42
  • Ocean and terrestrial water: 1
  • Sedimentary formation water: less than 1
  • Thermal spring water: 3 to 11

3He/4He isotope chemistry is being used to date groundwaters, estimate groundwater flow rates, track water pollution, and provide insights into hydrothermal processes, igneous geology and ore genesis.

Uranium-series isotopes

U-series isotopes are unique amongst radiogenic isotopes because, being in the U-series decay chains, they are both radiogneic and radioactive. Because their abundances are normally quoted as activity ratios rather than atomic ratios, they are best considered separately from the other radiogenic isotope systems.

Protactinium/Thorium - 231Pa / 230Th

Uranium is well mixed in the ocean, and its decay produces 231Pa and 230Th at a constant activity ratio (0.093). The decay products are rapidly removed by adsorption on settling particles, but not at equal rates. 231Pa has a residence equivalent to the residence time of deep water in the Atlantic basin (around 1000 yrs) but 230Th is removed more rapidly (centuries). Thermohaline circulation effectively exports 231Pa from the Atlantic into the Southern Ocean, while most of the 230Th remains in Atlantic sediments. As a result, there is a relationship between 231Pa/230Th in Atlantic sediments and the rate of overturning: faster overturning produces lower sediment 231Pa/230Th ratio, while slower overturning increases this ratio. The combination of δ13C and 231Pa/230Th can therefore provide a more complete insight into past circulation changes.

Anthropogenic isotopes

Tritium/helium-3

Tritium was released to the atmosphere during atmospheric testing of nuclear bombs. Radioactive decay of tritium produces the noble gas helium-3. Comparing the ratio of tritium to helium-3 (3H/3He) allows estimation of the age of recent ground waters.

See also

Notes

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References

General

Stable isotopes

3He/4He

  • Burnard P.G., Farley K.A., & Turner G., 1998. "Multiple fluid pulses in a Samoan harzburgite", Chemical Geology, 147: 99-114.
  • Kirstein L. & Timmerman M., 2000. "Evidence of the proto-Iceland lume in northwestern Ireland at 42Ma from helium isotopes", Journal of the Geological Society, London, 157: 923-927.
  • Porcelli D. & Halliday A.N., 2001. "The core as a possible source of mantle helium", Earth and Planetary Science Letters, 192: 45-56.

Re-Os

  • Arne D., Bierlein F.P., Morgan J.W., & Stein H.J., 2001. "Re-Os dating of sulfides associated with gold mineralisation in central Victoria, Australia", Economic Geology, 96: 1455-1459.
  • Martin C., 1991. "Osmium isotopic characteristics of mantle-derived rocks", Geochimica et Cosmochimica Acta, 55: 1421-1434.

External links

Template:Chronology

  1. 1.0 1.1 1.2 1.3 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534
  2. 2.0 2.1 2.2 Template:Cite web
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    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

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    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

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  4. 4.0 4.1 One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

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  5. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

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    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  6. One of the biggest reasons investing in a Singapore new launch is an effective things is as a result of it is doable to be lent massive quantities of money at very low interest rates that you should utilize to purchase it. Then, if property values continue to go up, then you'll get a really high return on funding (ROI). Simply make sure you purchase one of the higher properties, reminiscent of the ones at Fernvale the Riverbank or any Singapore landed property Get Earnings by means of Renting

    In its statement, the singapore property listing - website link, government claimed that the majority citizens buying their first residence won't be hurt by the new measures. Some concessions can even be prolonged to chose teams of consumers, similar to married couples with a minimum of one Singaporean partner who are purchasing their second property so long as they intend to promote their first residential property. Lower the LTV limit on housing loans granted by monetary establishments regulated by MAS from 70% to 60% for property purchasers who are individuals with a number of outstanding housing loans on the time of the brand new housing purchase. Singapore Property Measures - 30 August 2010 The most popular seek for the number of bedrooms in Singapore is 4, followed by 2 and three. Lush Acres EC @ Sengkang

    Discover out more about real estate funding in the area, together with info on international funding incentives and property possession. Many Singaporeans have been investing in property across the causeway in recent years, attracted by comparatively low prices. However, those who need to exit their investments quickly are likely to face significant challenges when trying to sell their property – and could finally be stuck with a property they can't sell. Career improvement programmes, in-house valuation, auctions and administrative help, venture advertising and marketing, skilled talks and traisning are continuously planned for the sales associates to help them obtain better outcomes for his or her shoppers while at Knight Frank Singapore. No change Present Rules

    Extending the tax exemption would help. The exemption, which may be as a lot as $2 million per family, covers individuals who negotiate a principal reduction on their existing mortgage, sell their house short (i.e., for lower than the excellent loans), or take part in a foreclosure course of. An extension of theexemption would seem like a common-sense means to assist stabilize the housing market, but the political turmoil around the fiscal-cliff negotiations means widespread sense could not win out. Home Minority Chief Nancy Pelosi (D-Calif.) believes that the mortgage relief provision will be on the table during the grand-cut price talks, in response to communications director Nadeam Elshami. Buying or promoting of blue mild bulbs is unlawful.

    A vendor's stamp duty has been launched on industrial property for the primary time, at rates ranging from 5 per cent to 15 per cent. The Authorities might be trying to reassure the market that they aren't in opposition to foreigners and PRs investing in Singapore's property market. They imposed these measures because of extenuating components available in the market." The sale of new dual-key EC models will even be restricted to multi-generational households only. The models have two separate entrances, permitting grandparents, for example, to dwell separately. The vendor's stamp obligation takes effect right this moment and applies to industrial property and plots which might be offered inside three years of the date of buy. JLL named Best Performing Property Brand for second year running

    The data offered is for normal info purposes only and isn't supposed to be personalised investment or monetary advice. Motley Fool Singapore contributor Stanley Lim would not personal shares in any corporations talked about. Singapore private home costs increased by 1.eight% within the fourth quarter of 2012, up from 0.6% within the earlier quarter. Resale prices of government-built HDB residences which are usually bought by Singaporeans, elevated by 2.5%, quarter on quarter, the quickest acquire in five quarters. And industrial property, prices are actually double the levels of three years ago. No withholding tax in the event you sell your property. All your local information regarding vital HDB policies, condominium launches, land growth, commercial property and more

    There are various methods to go about discovering the precise property. Some local newspapers (together with the Straits Instances ) have categorised property sections and many local property brokers have websites. Now there are some specifics to consider when buying a 'new launch' rental. Intended use of the unit Every sale begins with 10 p.c low cost for finish of season sale; changes to 20 % discount storewide; follows by additional reduction of fiftyand ends with last discount of 70 % or extra. Typically there is even a warehouse sale or transferring out sale with huge mark-down of costs for stock clearance. Deborah Regulation from Expat Realtor shares her property market update, plus prime rental residences and houses at the moment available to lease Esparina EC @ Sengkang
  7. Rollinson, H.R. (1993). Using Geochemical Data: Evaluation, Presentation, Interpretation Longman Scientific & Technical. ISBN 978-0-582-06701-1
  8. 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.

    My blog: http://www.primaboinca.com/view_profile.php?userid=5889534