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{{Statistical mechanics|cTopic=[[Statistical ensemble (mathematical physics)|Ensembles]]}}
 
The '''isoenthalpic-isobaric ensemble''' (constant [[enthalpy]] and constant [[pressure]] ensemble) is a [[statistical mechanics|statistical mechanical]] [[statistical ensemble|ensemble]] that maintains constant enthalpy <math>H \,</math> and constant pressure <math>P \,</math> applied. It is also called the <math>NpH</math>-ensemble, where the number of particles <math>N \,</math> is also kept as a constant. It was developed by physicist H. C. Andersen in 1980.<ref>Andersen, H. C. ''Journal of Chemical Physics'' 72, 2384-2393 (1980).</ref> The ensemble adds another [[degrees of freedom (physics and chemistry)|degree of freedom]], which represents the variable volume <math>V \,</math> of a system to which the coordinates of all particles are relative. The volume <math>V \,</math> becomes a dynamical [[Variable (mathematics)|variable]] with [[potential energy]] and [[kinetic energy]] given by <math>PV \,</math>.<ref>Hwee, Chiang Soo. [http://dynamicslab.mpe.nus.edu.sg/dynamics/project0304/thesis0304/Mechanical%20behavior%20of%20bio-cell%20in%20living%20system%20using%20molecular%20dynamics.pdf "Mechanical behavior of peptides in living systems using molecular dynamics."]</ref> The enthalpy <math>H=E+PV \,</math> is a [[conserved quantity]].<ref>[http://www.fisica.uniud.it/~ercolessi/md/md/node43.html Other Statistical Ensembles]</ref>
 
== References ==
<references/>
{{Statistical mechanics topics}}
 
{{DEFAULTSORT:Isoenthalpic-isobaric ensemble}}
[[Category:Statistical ensembles]]
 
 
{{physics-stub}}

Revision as of 04:38, 23 January 2014

Template:Statistical mechanics

The isoenthalpic-isobaric ensemble (constant enthalpy and constant pressure ensemble) is a statistical mechanical ensemble that maintains constant enthalpy and constant pressure applied. It is also called the -ensemble, where the number of particles is also kept as a constant. It was developed by physicist H. C. Andersen in 1980.[1] The ensemble adds another degree of freedom, which represents the variable volume of a system to which the coordinates of all particles are relative. The volume becomes a dynamical variable with potential energy and kinetic energy given by .[2] The enthalpy is a conserved quantity.[3]

References

  1. ↑ Andersen, H. C. Journal of Chemical Physics 72, 2384-2393 (1980).
  2. ↑ Hwee, Chiang Soo. "Mechanical behavior of peptides in living systems using molecular dynamics."
  3. ↑ Other Statistical Ensembles

Template:Statistical mechanics topics


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