Molecular symmetry

In mathematics, the binary octahedral group, name as 2O or <2,3,4> is a certain nonabelian group of order 48. It is an extension of the octahedral group O or (2,3,4) of order 24 by a cyclic group of order 2, and is the preimage of the octahedral group under the 2:1 covering homomorphism $\operatorname {Spin} (3)\to \operatorname {SO} (3)$ of the special orthogonal group by the spin group. It follows that the binary octahedral group is a discrete subgroup of Spin(3) of order 48.

The binary octahedral group is most easily described concretely as a discrete subgroup of the unit quaternions, under the isomorphism $\operatorname {Spin} (3)\cong \operatorname {Sp} (1)$ where Sp(1) is the multiplicative group of unit quaternions. (For a description of this homomorphism see the article on quaternions and spatial rotations.)

Elements

Explicitly, the binary octahedral group is given as the union of the 24 Hurwitz units

$\{\pm 1,\pm i,\pm j,\pm k,{\tfrac {1}{2}}(\pm 1\pm i\pm j\pm k)\}$

with all 24 quaternions obtained from

${\tfrac {1}{\sqrt {2}}}(\pm 1\pm 1i+0j+0k)$

by a permutation of coordinates (all possible sign combinations). All 48 elements have absolute value 1 and therefore lie in the unit quaternion group Sp(1).

Properties

The binary octahedral group, denoted by 2O, fits into the short exact sequence

$1\to \{\pm 1\}\to 2O\to O\to 1.\,$

This sequence does not split, meaning that 2O is not a semidirect product of {±1} by O. In fact, there is no subgroup of 2O isomorphic to O.

The center of 2O is the subgroup {±1}, so that the inner automorphism group is isomorphic to O. The full automorphism group is isomorphic to O × Z₂.

Presentation

The group 2O has a presentation given by

$\langle r,s,t\mid r^{2}=s^{3}=t^{4}=rst\rangle$

or equivalently,

$\langle s,t\mid (st)^{2}=s^{3}=t^{4}\rangle .$

Generators with these relations are given by

$s=-{\tfrac {1}{2}}(1+i+j+k)\qquad t={\tfrac {1}{\sqrt {2}}}(1+i).$

Subgroups

The quaternion group consisting of the 8 Lipschitz units forms a normal subgroup of 2O of index 6. The quotient group is isomorphic to S₃ (the symmetric group on 3 letters). The binary tetrahedral group, consisting of the 24 Hurwitz units, forms a normal subgroup of index 2. These two groups, together with the center {±1}, are the only nontrivial normal subgroups of 2O.

The generalized quaternion group of order 16 also forms a subgroup of 2O. This subgroup is self-normalizing so its conjugacy class has 3 members. There are also isomorphic copies of the binary dihedral groups of orders 8 and 12 in 2O. All other subgroups are cyclic groups generated by the various elements (with orders 3, 4, 6, and 8).

Higher dimensions

The binary octahedral group generalizes to higher dimensions: just as the octahedron generalizes to the hyperoctahedron, the octahedral group in SO(3) generalizes to the hyperoctahedral group in SO(n), which has a binary cover under the map $\operatorname {Spin} (n)\to SO(n).$

See also

• binary polyhedral group
• binary cyclic group
• binary dihedral group
• binary tetrahedral group
• binary icosahedral group
• hyperoctahedral group

References

• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
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• 20 year-old Real Estate Agent Rusty from Saint-Paul, has hobbies and interests which includes monopoly, property developers in singapore and poker. Will soon undertake a contiki trip that may include going to the Lower Valley of the Omo.
  
  My blog: http://www.primaboinca.com/view_profile.php?userid=5889534