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In [[chemistry]], '''homogeneous catalysis''' is a sequence of reactions that involve a [[catalyst]] in the same phase as the [[reactants]]. Phase here refers to [[solid]], [[liquid]], vs [[gas]]. Most commonly, a homogeneous catalyst is codissolved in a [[solvent]] with the reactants. 
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===Acid catalysis===
 
{{main|acid catalysis}}
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The proton is the most pervasive homogeneous catalyst <ref>R.P. Bell "The Proton in Chemistry", Chapman and Hall, London, 1973. {{DOI| 10.1016/0022-2860(76)80186-X}}</ref> because water is the most common solvent. Water forms protons by the process of [[self-ionization of water]] In an illustrative case, acids accelerate (catalyse) the [[hydrolysis]] of [[ester]]s:
 
:CH<sub>3</sub>CO<sub>2</sub>CH<sub>3</sub> +  H<sub>2</sub><math>\overrightarrow{\leftarrow}</math> CH<sub>3</sub>CO<sub>2</sub>H +  CH<sub>3</sub>OH
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In the absence of acids, aqueous solutions of most esters do not hydrolyze at practical rates.
 
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===Organometallic chemistry===
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Processes that utilize soluble [[organometallic compound]]s as catalysts fall under the category of homogeneous catalysis, as opposed to processes that use bulk metal or metal on a solid support, which are examples of [[heterogeneous catalysis]]. Some well-known examples of homogeneous catalysis include [[hydroformylation]] and [[transfer hydrogenation]], as well as certain kinds of [[Ziegler-Natta]] polymerization and [[hydrogenation]].<ref>Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH: Weinheim. ISBN 978-3-527-29390-2</ref>  Homogeneous catalysts has also been used in a variety of industrial processes such as the [[Wacker process]] Acetaldehyde (conversion of [[ethylene]] to [[acetaldehyde]]) as well as the [[Monsanto process]] and the [[Cativa process]] for the conversion of [[MeOH]] and [[Carbon monoxide|CO]] to [[acetic acid]].


Many non-organometallic complexes are also widely used in catalysis, e.g. for the production of [[terephthalic acid]] from [[xylene]].
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===Other forms of homogeneous catalysis===
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[[Enzyme]]s are homogeneous catalysts that are essential for life but are also harnessed for industrial processes.  A well studied example [[carbonic anhydrase]], which catalyzes the release of CO<sub>2</sub> into the lungs from the blood stream.


==Contrast with heterogeneous catalysis==
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Homogeneous catalysis differs from [[heterogeneous catalysis]] in that the catalyst is in a different phase than the reactants. One example of heterogeneous catalysis is the petrochemical [[alkylation]] process, where the liquid reactants are immiscible with a solution containing the catalyst. Heterogeneous catalysis offers the advantage that products are readily separated from the catalyst, and heterogeneous catalysts are often more stable and degrade much slower than homogeneous catalysts. However, heterogeneous catalysts are difficult to study, so their reaction mechanisms are often unknown.<ref>G. O. Spessard and G. L. Miessler "Organometallic Chemistry", Prentice Hall, Upper Saddle River, NJ, 1997, pp. 249-251.  </ref>  
 
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[[Enzyme]]s possess properties of both homogeneous and heterogeneous catalysts.  As such, they are usually regarded as a third, separate category of catalyst.
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